The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
On the other hand, there are large numbers of compounds, especially
among organic substances, which do not appear to ionize to a
measurable extent and whose actions, in large part at least, appear
to be the actions of ‹non-ionized molecules›. It is characteristic
that most of these actions take place at ‹slow›, very frequently
easily measurable, rates of speed. Critical study shows that even
for such actions ionization often plays a very important rôle, at
least in some of their stages, and throughout the field of organic
chemistry the ‹intimate relations› between ‹electrical phenomena
and chemical activity can be readily recognized›.[146] But these
relations are not obvious ones and do not, as yet, play a dominant
rôle. It is because analytical chemistry deals predominantly with the
reactions of ‹ionogens›, that the study of the ‹reactions of ions›
will demand our extended attention.
«Reactions in Non-aqueous Solutions.»—Kahlenberg[147] has made some
interesting and important, although not conclusive, contributions
to the problem of chemical activity of ionogens in non-aqueous
solutions. He has found, for instance, that zinc, left in contact
with a benzene solution of hydrogen chloride carefully freed from
moisture, displaces hydrogen.[148] Cadmium, aluminium and magnesium,
on the other hand, do not evolve hydrogen in such a solution.[149]
The solution shows an enormous resistance to the passage of an
electric current, and the conclusion is drawn by Kahlenberg that the
liberation of hydrogen is due to the action of non-ionized hydrogen
chloride on the zinc.
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