The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
In the following chapters and, indeed, throughout our further work,
we shall continually meet additional instances of the quantitative
relation between chemical activity and ionization. In fact, the
results obtained in the field of quantitative measurement of chemical
action, of which the above are single instances, have demonstrated,
more than anything else, the value of the theory of ionization to
chemistry and the necessity of taking it into account in expressing
the results of chemical action in mathematical terms. [p083]
«Summary.»—Measurements made, then, in three great and independent
fields of investigation, ‹electrical conductivity›, ‹osmotic
pressure› and the allied relations, and ‹chemical activity›,
bring independent testimony to the correctness of the fundamental
assumptions of Arrhenius's theory of ionization. In the quantitative
study of solutions of electrolytes, wherever secondary disturbing
influences are eliminated or are taken into account as far as
possible, the three lines of investigation give results which
agree satisfactorily[143] as to the degree of ionization of the
electrolytes under examination. With the aid of this theory,
‹predictions› of the course of chemical action may now be made more
definitely and with more assurance than ever before in the history of
chemistry.
«Chemical Activity of Non-ionized Molecules.»—The conclusion
reached, on the basis both of qualitative and, particularly, of
quantitative evidence, that the reactions of salts, acids and bases
(ionogens) in aqueous solutions (the so-called salt reactions) are
the actions of the ions and not of the non-ionized molecules, does
not necessarily mean that the non-ionized molecules are altogether
inactive chemically. Some chemists believe that ions have only the
advantage of an ‹enormously greater degree of reactivity›.[144]
If the atoms in a molecule carry electric charges even prior to
their separation (ionization), as expressed for instance by the
formula H^{+}Cl^{−} for hydrogen chloride (p. 43), it can be
readily seen that an action[145] resulting from the collision
of a molecule of hydrogen chloride with a molecule of potassium
hydroxide H^{+}Cl^{−} + HO^{−}K^{+} ⇄ K^{+}Cl^{−} + HO^{−}H^{+}
would, in some respects, resemble the ionic action H^{+} + Cl^{−} +
K^{+} + HO^{−} ⇄ K^{+} + Cl^{−} + HOH. The latter would probably
have the advantage of a considerably smaller resistance to the
action, and consequently of a far greater speed. ‹But the question of
supreme importance and interest to chemistry is the question as to
which actions are found experimentally to be of moment in any given
case.› Now, a great mass of corroborative evidence shows that for
the interactions of ionogens in aqueous solutions the ionic actions,
probably on account of their enormous speeds, ‹are the important
ones›. [p084]
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