The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
[127] Gore, ‹Proc. Royal Soc.›, «14», 204 (1841). Gore found that
aluminium was dissolved and that sodium and potassium were attacked
by the gas, even before its liquefaction. It is uncertain whether
these positive reactions are reactions of absolutely anhydrous
hydrogen chloride or the result of the presence of moisture in
the experiments in question, since Cohen [‹Chem. News›, «54», 305
(1896)], drying the gas more carefully than did Gore, found, in
contrast to the latter, that metallic sodium may be exposed for
several weeks to dry hydrogen chloride gas and retain its lustre.
In all experiments demanding the rigorous exclusion of moisture,
more weight must be attached to negative results (showing lack of
activity) than to positive results. [‹Cf.› the controversy between
Baker, ‹loc. cit.›, and Gutmann, ‹Liebig's Ann.›, «299», 3 (1898)].
[128] Nernst's ‹Theoretical Chemistry›, p. 375. Kablukoff, ‹Z.
phys. Chem.›, «4», 430 (1889).
[129] In regard to the behavior of zinc, see below, p. 84. (‹Cf.›
Kahlenberg, ‹J. Phys. Chem.›, «6», 13 (1902) (‹Stud.›).)
[130] For a fuller discussion of the benzene solution see p. 84.
[131] The ‹acid› character, in particular, is due to the
hydrogen-ion, H^{+}; see below.
[132] The fusion is conveniently made in a platinum dish; the dish
and a platinum cathode are connected with the lighting circuit and
an electric lamp.
[133] See Smith, ‹Inorganic Chemistry›, pp. 550, 569, 578, 588,
608, 610, 683: ‹College Chemistry›, 361, 373, 380, 389, 404, 405,
443 («Stud.»).
[134] ‹J. Chem. Soc.› (Abstracts) (London), «40», 504 (1881).
[135] For positive evidence of the ionizing power of light, see
Haber, ‹Z. Elektrochem.›, «11», 847 (1905). For evidence as to the
negligible rôle of ionization in the combination of chlorine and
hydrogen, see Mellor, ‹Chemical Statics and Dynamics› (1904), p.
290.
[136] The apparatus described by A. A. Noyes and Blanchard for
comparing acids is used [‹J. Am. Chem. Soc.›, «22», 737 (1900)].
[137] The conductivity depends in this case chiefly on the
migration of the ‹fast moving hydroxide ions› (p. 56), common to
the three bases. There is little difference in the rates at which
the cations move.
[138] The water should be free from carbonic acid.
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