The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
[139] The various indicators show different, specific ‹degrees
of sensitiveness to acids (to hydrogen ions) and to bases
(to hydroxide ions)›. That is, different concentrations of
hydrogen-ion or of hydroxide-ion are required to change their
colors. As they are particularly useful in demonstrating ‹varying›
concentrations of these ions, they will frequently be used in
illustrating conclusions reached in the course of our work, just
as they are used extensively in practical analysis. The following
tables are intended to give some definite information on this
valuable quality. The fourth column of the first table shows the
concentration of ‹hydrogen-ion›, required to change the color of
the indicator from the tint given in the second column to the tint
given in the third column. The second table gives, similarly, the
concentrations of hydroxide-ion required to produce the changes of
tint indicated. The tables refer to results obtained when 0.1 c.c.
(about two drops) of a 0.1 to 0.15% solution of the indicator is
added to 10 c.c. of the solution examined.
TABLE OF SENSITIVENESS TO ACIDS (TO HYDROGEN-ION)
Indicator. From to Concentration
H^{+}.
Phenolphthaleïn Pink Colorless 10E−9
Azolitmin[A] (litmus) Violet Violet ‹pink› 1E−6
Methyl orange Yellow Reddish orange 1E−3 – 0.1E−3
TABLE NOTE:
A. Azolitmin is an important component of litmus.
TABLE OF SENSITIVENESS TO BASES (TO HYDROXIDE-ION)
Indicator. From to Concentration
HO^{−}.
Phenolphthaleïn Colorless Pink 10E−6
Azolitmin Violet Violet ‹blue› 1E−6 – 0.1E−6
Methyl orange Orange Yellow 1E−9
It is clear that of the three indicators given in the table,
phenolphthaleïn is the most sensitive to acids, methyl orange the
most sensitive to bases. An extended table of the sensitiveness
of many indicators, on which the above tables are based, is given
by Salm, ‹Z. phys. Chem.›, «57», 471 (1907). The ‹theories› (of
Ostwald, Bernthsen, and others) regarding the ‹color changes›,
and the ‹theory› (of Ostwald) concerning the ‹sensitiveness of
indicators›, are discussed (with references to the literature)
by Stieglitz, ‹J. Am. Chem. Soc.›, «25», 1117 (1903). Later
modifications of the views on color changes are discussed in
papers by Stieglitz, ‹Am. Chem. J.› «39», (1908), and by Acree,
‹ibid.›, «37», «39», «42», and in these papers references to the
literature will be found. For investigations on the sensitiveness
of indicators, see McCoy, ‹ibid.›, «31», 508 (1904), Salm, ‹loc.
cit.›, and A. A. Noyes, ‹J. Am. Chem. Soc.›, «32», 815 (1910).
[140] ‹Z. phys. Chem.›, «2», 289 (1888). Note the remarks in the
footnote following.
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