The crude petroleum oil is a liquid and cannot be sifted on screens as
is the crude gravel, but nature has given it properties in consequence
of which it may be separated into its constituents almost as easily
as is the gravel. These properties are the different boiling points
of the several constituents. Thus, when water or any other single
liquid is heated it continues to increase in temperature until boiling
begins, after which its temperature remains the same, no matter how
rapidly the heat is applied, until all of the liquid has been boiled
away. When petroleum is heated, however, it begins to boil at a very
low temperature, a temperature hardly hot enough to injure the skin,
in some cases. It is not the whole of the petroleum which is boiling,
however, but only the very lightest part of it, that is, the gasoline
or naphtha. If the temperature were to be held constant for a short
length of time all of the gasoline would have been boiled off, and
although the liquid would be just as hot as it was before, the boiling
would cease entirely. If the heating is now continued, however, and the
temperature of the oil raised to some higher figure, it again begins
to boil and now it is the kerosene constituent of the crude petroleum
which is being converted into vapour and driven out of the liquid.
After a time all of this kerosene will be gone, and as before, the
liquid, although still at the same temperature at which it has just
previously been actively boiling, remains quiescent. In this fashion
the various constituents of the crude petroleum may be separated from
one another by a “sifting” operation somewhat similar to that used to
separate sand from gravel and gravel from rock, except that instead
of employing screens to effect the separation there is employed an
apparatus in which the heat of the oil can be gradually increased
and the products, which are successively driven off in this fashion,
separated from one another.
The apparatus commonly employed for this purpose is called a “still”
and consists merely of a steel receptacle, usually in the form of a
horizontal cylinder, much like a simple steam boiler. These stills
have been developed to large capacity, some of them holding upwards
of 50,000 wine gallons of oil at one time. The still is mounted over
a furnace which is usually heated by coal just as an ordinary steam
boiler. In this still the temperature of the crude petroleum is
gradually raised and with each elevation in temperature a different
product is boiled or driven off the mass of liquid until finally
nothing remains in the still except a small quantity of black residue
which is known as petroleum coke.
Public-domain text, read in full here on John Shaqi.
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