The next product which is driven off from the crude oil after all of
the kerosene has been removed is a somewhat heavy and discoloured, but
free flowing oil, known as “gas oil.” Gas oil is seldom sold at retail
and the general public has very little knowledge of it. Its main use
is for the manufacture of city gas, auxiliary to coal, the products of
which form the base of city gas.
The next product after the gas oil and the last important product of
crude petroleum is the lubricating oil distillate, which is known as
“paraffine distillate” for the reason that it contains the paraffine
wax.
With the exception of the gas oil, which by reason of the uses to which
it is put does not usually require any further treatment, the products
thus roughly separated from the crude petroleum each need not only
further separation, but actual chemical purification to prepare them
for the market.
Considering these products in the order in which they are derived
from the crude petroleum, the gasoline or naphtha fraction is often
subjected to a second distillation by which it is further “sifted” into
light, intermediate and heavy naphthas. It is customary to conduct this
second distillation process by steam heat instead of by fire, since
the gasoline or naphtha fraction boils at such a low temperature that
it is unnecessary to resort to a furnace and furthermore, the quality
of the product is thought to be better if the second distillation is
conducted with steam. Following this second distillation the naphtha
or gasoline is subjected to chemical purification which involves
treatment with sulphuric acid, with sodium hydrate, sodium plumate
and filtration through Fuller’s Earth--a species of clay which has
been found to have not only a mechanical but probably also a chemical
purifying and decolourizing action. There is a considerable variation
in the purification or refining method employed by the different
refiners, but the foregoing treatments are the principal ones now in
vogue. The marketable products produced from the crude gasoline or
naphtha distillate by this re-distillation and purification process
are principally as stated--light naphthas, intermediate naphthas and
heavy naphthas. The light naphthas range from petroleum ether, an
exceedingly sweet-smelling and volatile liquid to aviation gasoline,
especially suitable for use in aeroplane motors under extreme
conditions of temperature and power development. The intermediate
naphtha is the ordinary gasoline of commerce, principally used as fuel
for automobile engines. The heavy naphtha is that often sold under the
name of benzine, cleaners’ naphtha, solvent naphtha or varnish makers’
and painters’ naphtha. As these names indicate, the heavy naphtha
is principally used in the manufacture of paints and varnishes, for
dry-cleaning and as a solvent in the chemical industries.
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