A drop of wine falls into a glass of water; whatever may be the law of
the internal motion of the liquid, we shall soon see it colored of a
uniform rosy tint, and however much from this moment one may shake it
afterwards, the wine and the water do not seem capable of again
separating. Here we have the type of the irreversible physical
phenomenon: to hide a grain of barley in a heap of wheat, this is easy;
afterwards to find it again and get it out, this is practically
impossible. All this Maxwell and Boltzmann have explained; but the one
who has seen it most clearly, in a book too little read because it is a
little difficult to read, is Gibbs, in his `Elementary Principles of
Statistical Mechanics.'
For those who take this point of view, Carnot's principle is only an
imperfect principle, a sort of concession to the infirmity of our
senses; it is because our eyes are too gross that we do not distinguish
the elements of the blend; it is because our hands are too gross that we
can not force them to separate; the imaginary demon of Maxwell, who is
able to sort the molecules one by one, could well constrain the world to
return backward. Can it return of itself? That is not impossible; that
is only infinitely improbable. The chances are that we should wait a
long time for the concourse of circumstances which would permit a
retrogradation; but sooner or later they will occur, after years whose
number it would take millions of figures to write. These reservations,
however, all remained theoretic; they were not very disquieting, and
Carnot's principle retained all its practical value. But here the scene
changes. The biologist, armed with his microscope, long ago noticed in
his preparations irregular movements of little particles in suspension;
this is the Brownian movement. He first thought this was a vital
phenomenon, but soon he saw that the inanimate bodies danced with no
less ardor than the others; then he turned the matter over to the
physicists. Unhappily, the physicists remained long uninterested in this
question; one concentrates the light to illuminate the microscopic
preparation, thought they; with light goes heat; thence inequalities of
temperature and in the liquid interior currents which produce the
movements referred to. It occurred to M. Gouy to look more closely, and
he saw, or thought he saw, that this explanation is untenable, that the
movements become brisker as the particles are smaller, but that they are
not influenced by the mode of illumination. If then these movements
never cease, or rather are reborn without cease, without borrowing
anything from an external source of energy, what ought we to believe? To
be sure, we should not on this account renounce our belief in the
conservation of energy, but we see under our eyes now motion transformed
into heat by friction, now inversely heat changed into motion, and that
without loss since the movement lasts forever. This is the contrary of
Carnot's principle.
Public-domain text, read in full here on John Shaqi.
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