The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
The simple apparatus with which such determinations are made is due to
the physicist Kundt. It consists of a glass tube, through one end of
which a glass rod passes, so that half the rod is enclosed in the tube,
while the other half projects outside it. In the experiments on argon,
the rod was sealed into the tube; in other cases, it is better to
attach it with indiarubber, or to cause the rod to pass through a cork.
The open end of the tube is connected with a supply of the gas, so
that, after the tube has been pumped empty of air, the gas, in a pure
and dry condition, can be admitted. Some light powder (and for this
purpose lycopodium dust--the dried spores of a species of fungus--is
best) is placed in the tube, and distributed uniformly throughout it,
so that when the latter is in a horizontal position, a streak of the
powder lies along it from end to end. The portion of rod outside the
tube is rubbed with a rag wetted with alcohol, when it emits a shrill
tone or squeak, due to longitudinal vibrations; the pitch of the tone
depends, naturally, on the length of the rod, a long rod giving a
deeper tone than a short one. The vibrations of the rod set the gas in
the tube in motion, and the sound-waves are conveyed from end to end of
the tube through the gas. As the tube is closed at the end through
which the gas was admitted, these waves echo back through it; and a
great deal of care must be taken to make the echo strengthen the waves,
so that the compressions produced by the back waves are coincident in
position with the compressions produced by the forward waves travelling
onwards from the rod. The gas, could we see it, would represent
portions compressed and portions rarefied at regular intervals along
the tube. Where the gas is compressed, it gathers the lycopodium dust
together in small heaps, the position of each heap signifying a node
of compression. Hence, comparing the distances between the nodes of
compression for any gas and for air, we find the relative wave-lengths
of sound in the two gases; and, as the velocity of sound in air has
been accurately measured, we thus determine the velocity of sound-waves
in the gas under experiment.
Such experiments were made by Kundt and by his co-worker Warburg on
mercury gas, and they found that in this case the value of γ was
1·67; that is, in the equation
γ = _c_^{2}_d_/_p_
the value 1·67 had to be ascribed to γ, in order to render it
equal to the product of the square of the velocity into the density,
divided by the pressure.
Similar experiments with argon led to the same result as Kundt and
Warburg found for mercury gas; but the calculation becomes more
simple if it is allowable to take for granted that the elasticity,
or alteration of pressure produced by unit alteration of volume, is
identical in the case of argon and air. The full equations are--
__________________________
_n_λ_{air} = _c__{air} = √γ(_p_/_d_)(1 + _at_)_{air},
and
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