The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
This method, however, can be employed only when an unlimited supply of
gas is at disposal, for it entails the use of large vessels, and the
compressed gas must be allowed to escape into the atmosphere, and is
lost. There is, fortunately, another method by which the same results
can be obtained, and which requires only a small amount of gas.
Sir Isaac Newton calculated that the velocity of sound in a gas was
dependent on its pressure and on its density, in such a manner that
__________
_c_ = √ (_p_/_d_),
where _c_ stands for velocity (celerity), _p_ for pressure, and _d_
for density. When waves of sound are transmitted through air, the
air is compressed in parts and rarefied in parts, in such a manner
that compression follows rarefaction very rapidly, that part which is
compressed at one instant being rarefied at the next, compressed again
at a third, and rarefied at a fourth, and so on. Laplace was the first
to point out that during such rapid changes of pressure as occur while
a sound-wave is passing, the pressure will not rise proportionally to
the density, as would be the case if Boyle’s law were followed; for
on sudden rise of pressure the temperature of the compressed portion
of the gas will be increased; and, correspondingly, on sudden fall
of pressure, the wave of compression having passed, the temperature
will fall. He showed that instead of two pressures being inversely
proportional to their two volumes, under such circumstances, as they
are according to Boyle’s law, or
_p_/_p__{1} = _v__{1}/_v_,
they must be inversely proportional to the volumes raised to a power,
the numerical expression of which is the ratio of the specific heats of
the two gases, =γ=, thus:
_p_/_p__{1} = (_v__{1}/_v_)^γ;
or as
_v__{1} : _v_ :: _d_ : _d__{1},
___________
_c_ = √( γ_p_/_d_), and γ = _c_^2_d_/_p_.
The ratio of the two specific heats can therefore be determined by
finding the velocity of sound in the gas, and by noting at the same
time its density and its pressure.
To determine the velocity of sound in a gas, it is not necessary to
adopt the plan which has been successfully carried out with air; that
is, to make a sudden sound at one spot and to measure the interval
of time which the sound takes to travel to another spot some miles
distant. There is a simpler method, depending on the fact that the
lengths of the waves of compression and rarefaction are proportional
to the velocity of the sound. So that, knowing the velocity of sound
in air, the velocity in any other gas may be found by determining the
relative length of the sound-waves in air and in that gas.
[Illustration: FIG. 4.]
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