The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
It has already been mentioned that the rise of pressure of argon with
rise of temperature has been carefully measured by Drs. Randall and
Kuenen, and that it is quite normal; no sign of splitting has been
observed. But the range of temperature was not great (it was only from
0° to 280°), and it is quite possible that the change, if there was
one, was so minute as to have escaped detection. Again, a more delicate
method of detecting such a change is in the measurement of the ratio of
the specific heats. The most trustworthy number obtained was 1·659
for the ratio, instead of 1·667, the theoretical figure. A mixture of
5 per cent of diatomic molecules should have reduced this ratio to
1·648. Here the evidence is, however, inconclusive. But on the whole,
the presumption is against the hypothesis that argon is a mixture of
monatomic with diatomic molecules.
It still remains for us, therefore, to account for the fact that in the
periodic table there is no place for argon, provided it be insisted
on that the elements must follow each other in the numerical order
of their atomic weights. If the numbers in the table actually showed
regular intervals, or if there were any regularity to be detected in
their differences, argon might be regarded as of wholly exceptional
behaviour. But this is not so. Argon is an extreme instance of
divergence, but similar divergences, though not of equal magnitude, are
common.
In attempting to offer an explanation of such anomalies, it must be
remembered that the question is in itself a far-reaching one; and that
although argon has served to direct attention anew to the anomalies
of the periodic table, yet these anomalies existed before argon was
discovered. It is necessary above all things to be clear as to what is
under discussion. We speak of “atomic weights,” or “atomic masses.”
What is meant precisely by these expressions?
By mass, we understand that property of a body, in virtue of which,
when acted on by a certain force for a certain time, it acquires a
certain velocity. The product of the mass into half the velocity
squared, or ½MV^2 (where M and V stand respectively for mass and for
velocity), is what is termed kinetic energy. If the mass chosen be 1
gram, and the velocity 1 centimetre per second, the unit of energy
is the product; it is termed an erg. The same unit of energy, the
erg, is derived by the action of unit force, termed 1 dyne, through
unit length, 1 centimetre. We have thus two equations, where F and L
represent force and length,
Kinetic Energy = ½(MV)^2 and Linear Energy = FL.
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