The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
Now we choose mass as a unit of measure of the _quantity of material_;
and we are justified in doing so, because experiments have shown that
material, confined in a closed space, does not appreciably alter its
mass. The mass is proportional to the _weight_, generally measured as
the force exerted at some definite latitude on the earth’s surface,
tending to pull the body towards the centre of the earth. This force
is equal to about 981 dynes at London. There is no known reason
why mass and weight should be proportional to each other; for the
cause of the attraction of the earth has never been satisfactorily
elucidated. We therefore use weight, or the attraction of the earth, as
a convenient means of determining the relative masses of two objects.
Hence it appears rational to prefer the expression “atomic weight” to
“atomic mass,” seeing that the former represents the actual result of
experiment, and also because we are dealing in atomic weights with
relative numbers. But this is really a matter of choice.
The atomic weights therefore represent the relative masses in which
the elements generally unite. They often, however, unite in multiples
of these weights, as formulated by Dalton’s second law. The weights,
arranged in numerical order in columns, give us the periodic table.
Now energy can be measured in other units besides those of force and
mass. Heat is one form of energy, and it is measured by an interval of
temperature, and by a property which we term specific heat. It happens
that the latter property varies, not with the mass of the substance
heated, but with its atom, so that all elements have approximately
the same atomic heat; that is, quantities of elements proportional in
mass to their atomic weights require approximately equal increments
of heat to raise their temperature through an equal interval, say 1°.
This is the formulation of Dulong and Petit’s law previously alluded
to. But here we meet with irregularities, which have up till now
defied classification. The heat imparted to an aggregation of atoms
is not expended solely in raising their temperature; other work is
done also, as is generally supposed, in the nature of expansion, or
separation of parts, as in overcoming the attraction between the atoms
in the molecule, or in imparting special motion to the atoms; such
work, however, involves an expenditure of energy which is either very
small in proportion to the total energy imparted as heat, or is nearly
the same for all elements. At present we cannot decide between these
alternatives, owing to the lack of knowledge of the nature of liquids
and solids. The main fact, however, is incontestable: that the heat
energy required to raise different elements through the same interval
of temperature is the same, not for equal masses or weights of the
substances, but for their _atomic_ masses.
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