The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
Again, many compounds when dissolved in water conduct an electric
current, while they themselves are decomposed; and the different
ingredients of the compound are often deposited at the points where the
electric current enters or leaves the liquid. Where they are not so
deposited, it is usually because of their action on the solvent water.
Now Faraday found that when elements are deposited, equal quantities of
electricity are conveyed either by equal numbers of atoms or by some
simple fraction of these numbers. To this fraction we apply the term
_valency_. Thus we say that an atom of oxygen is bivalent, or a dyad,
because it conveys twice as much electricity through the liquid in
which it is present as an atom of hydrogen, which is termed univalent,
or a monad. Here we see a direct connection between the conveyance of
an electric charge and the atomic weight. The electric unit of quantity
is in fact defined as that which can be conveyed by a certain weight of
hydrogen, by 8 times that weight of oxygen, by 108 times that weight of
silver, and so on. Therefore the electrical unit is connected, not with
unit of mass, or with the gravitational unit, but with the atomic unit.
We have therefore a number of systems, each capable of being equated
to a unit of energy, but of which the terms are in some as yet unknown
way related to each other, and often more directly than they can be
related to mass and weight. This relation is only an approximate one
in the case of specific heats; it appears to be an absolute one in the
conveyance of electrical energy. The arrangement of the elements in
the periodic table must therefore be considered by the light of such
general views.
I would venture to suggest, as a tentative method of solving this
problem, that it be considered whether mass or weight are such
invariable properties of matter as have generally been taken for
granted. That the relative weights or masses in which elements combine
always retain their invariable proportion is true, so far as we can
determine; but it must be remembered that we cannot cause them to
combine except under a very limited series of conditions. For example,
the act of combination equalises the temperature of two combining
atoms; it also, in all probability, equalises their electrical charges.
It is a legitimate speculation whether, could we maintain a difference
in their temperature or in their electric potential, their atomic
weights might not also change. Indeed, we are ignorant whether mass
is changed by alteration of temperature. Experiments made by Sir
John Airy, and interpreted by Professor Hicks, appear to show that
variation of temperature is not without some influence on gravitational
attraction. Others by Professor Landolt point in the same direction.
Public-domain text, read in full here on John Shaqi.
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