The Gases of the Atmosphere: The History of Their Discovery — John Shaqi
The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
3. All acids contain fire-air particles, for acids have great
similarity to each other. This is shown as follows:--Antimony made into
a calx by the sun’s rays with a burning-glass gives the same calx as
when it is evaporated repeatedly with nitric acid and converted into
“Bezoar-mineral,” _i.e._ oxide of antimony. And iron-rust obtained from
sulphide of iron appears to be formed by the union of the fire-air
particles with the metallic “sulphur” of the iron.
It has up till now been believed that sulphuric acid is an ingredient
of common sulphur. But this is unlikely, for sulphur has a sweetish,
and not an acid taste. Moreover, quite a different substance from
a vitriol (or sulphate) is obtained by melting together alkali and
sulphur; and no effervescence takes place during its preparation.
Sulphur, too, is precipitated out of the “liver of sulphur” (potassium
persulphide) by the addition of sulphuric acid. Now, were sulphuric
acid contained in sulphur, it would hinder the union of the sulphur
with the alkali.
It is to be noticed that the volatile sulphuric acid, from the
combustion of sulphur, is produced in the following way:--“The flame
of the burning sulphur consists, like every other flame, in the
violent motion of the sulphur particles with that of the nitro-aerial
particles; hence the sulphur particles, at first solid, become sharp
and acid, and probably form the ordinary ‘spirit of sulphur’ (sulphuric
acid). If this be not so, I know not in what manner this acid can be
produced; for, as has been shown, it is very improbable that it
previously existed in the mass of the sulphur before its deflagration.
Such a change also, in all probability, takes place in pyrites, when
it is converted to green vitriol; because pyrites yields sulphur on
distillation; and the green vitriol on distillation gives sulphuric
acid, leaving red colcothar (iron oxide) behind.”
Similarly, nitre appears to be a triple salt, formed by the union of
the fiery part of air with a salt-like substance existing in the
earthy material, together forming nitric acid; and this added to earthy
salts (alkali) yields ordinary nitre. “I have tried to show that
all acids consist of certain saline particles rendered fluid by the
nitro-aerial particles.”
4. Boyle has shown that a flame is extinguished more rapidly in
a vacuous space than in a confined space containing air; this is
obviously due to absence of nourishment in the air, rather than to
its choking by its own vapours; for in the vacuous vessel there is
evidently more space for such noxious vapours than in the air-filled
vessel, and yet the flame is more rapidly extinguished. Moreover, no
combustible matter can be kindled in a vacuum by means of a
burning-glass. But it must not be concluded that this fire-air
constitutes the whole of ordinary air; because a candle goes out in air
confined in a glass while a large quantity of air is still contained in
it.
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