The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
Rutherford begins his essay with an apt quotation from Lucretius:--
Denique res omnes debent in corpore habere
Aëra, quandoquidem rara sunt corpora et aër
Omnibus est rebus circumdatus appositusque.
He next proceeds to define the atmosphere as a pellucid thin fluid,
in which clouds float and vapours rise. Its necessity for animal
and vegetable life is acknowledged by all. It possesses weight and
elasticity. It can be fixed by other bodies; but the air obtained from
them by distillation differs from ordinary vital, salubrious air, and
is often termed mephitic or poisonous.
After acknowledging his debt to his illustrious preceptor Black, he
proceeds to quote from the latter to the effect that mephitic or fixed
air is the air which proves fatal to animals and extinguishes fire;
which is easily absorbed by quicklime and by alkaline salts; which
occurs in the Grotto del Cane, and in mineral waters; and which is
produced during exhalation from the lungs, by combustion, and during
certain kinds of fermentation. Its density, compared with that of
ordinary air, is as 15½ or 16 to 9; hence it can be kept for some
time in an open glass, and a candle lowered into it is extinguished. It
has an agreeable taste and smell; and it changes the colour of syrup of
violets from blue to purple. It prevents putrefaction, but putrefied
bodies are not made fresh by it. It possesses the power of combining
with lime, which acquires new properties as the result of its action.
Rutherford then recalls Black’s experiments on lime and on magnesia,
pointing out how these bases absorb fixed air, and how it can be
recovered from them and from its compounds with alkalies, sometimes by
heat, and always by the action of acids.
Rutherford next describes experiments which show that a mouse, placed
in atmospheric air, and left till dead, diminishes the volume of the
air by one-tenth; and that the residual air, on treatment with alkali,
loses one-eleventh of its volume. The residue extinguishes the flame of
a candle; but tinder continues to smoulder in it for a short time. It
is thus proved that after the whole of the fixed air has been withdrawn
by alkalies, the residue is still incapable of supporting life and
combustion.
Some burning bodies deprive air of its “salubrity” more easily than
others. The phosphorus of urine continues to glow in air in which a
candle has ceased to burn, or in which charcoal has burned until it is
extinguished. Even after the absorption of all fixed air by alkalies,
phosphorus burns, emitting clouds of the dry acid of phosphorus, which
can be absorbed by lime-water.
Public-domain text, read in full here on John Shaqi.
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