The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
in 1791, his house was burned, and he was obliged to escape to London
under an assumed name. After some years spent in the charge of a
meeting-house at Hackney, he left England for America. His opinions,
though by no means uncommon at the present day, were so antagonistic to
those of his English contemporaries that he was cut by his Fellows of
the Royal Society, and he therefore resigned his Fellowship. And this
feeling was in no way lessened by the action of the French Government
of the time, which made him a Citizen of the Republic, and even chose
him as a member of their Legislative Assembly. Arriving in America in
1795, he was well received, and settled at Northumberland, not far from
Philadelphia. There he died in 1804.
[Illustration: JOSEPH PRIESTLEY.]
In Priestley’s work on gases he employed the form of apparatus which
had been used by Mayow a century before. Such apparatus is indeed
generally used now: the flasks with bent delivery-tubes, the Wolff’s
bottles with two necks, and the pneumatic trough filled with water or
mercury were his chief utensils. By means of such apparatus, gases
can be collected in a state of comparative purity: they can be easily
transferred from one vessel to another, and substances which it is
desired to submit to their action can be readily introduced. Scheele,
on the other hand, employed less convenient methods: his gases were
generally collected in bladders, and their transference to bottles
must have been attended with the introduction of atmospheric air.
Scheele’s method was to allow a certain amount of gas to escape from
the generating flask in order to expel air; an empty bladder was then
tied over the neck, and the gas entered the bladder. When he wished to
transfer the gas to a bottle, the bladder was tied at some distance
from the neck, and its loose open end was secured by a string round the
neck of a bottle full of water. The string confining the gas was then
untied, and the bottle was inverted; the water ran into the bladder and
was replaced by gas. A cork was also enclosed in the bladder, and it was
possible to push this cork into the neck of the bottle and re-tie the
string which confined the gas; and then, by loosing the string which
secured the bottle to the bladder, the full bottle could be conveyed
away. This process is obviously a clumsy one, although in Scheele’s
hands it yielded splendid results; and the methods which Priestley had
borrowed from Mayow have attested their superiority by their survival.
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