The Gases of the Atmosphere: The History of Their Discovery — John Shaqi
The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
On the 1st of August 1774, Priestley heated by means of a burning-glass
red oxide of mercury. This was produced by heating mercury until it
oxidised, and therefore had been untouched by acids, or by any
substance which could have “imparted phlogiston” to atmospheric air.
The resulting air was insoluble in water, and supported combustion
better than common air, for a candle burned more brightly, and a piece
of red-hot wood sparkled in it. This air he also produced from “red
precipitate,” the product of heating nitrate of mercury; and at the
same time from red-lead, or minium. It differed from “modified nitrous
air,” in which a candle also burns brightly, inasmuch as shaking with
water the gases produced after a candle had burned for some time in
it did not deprive it of its power of supporting combustion; nor did
it diminish the bulk of common air, as the nitrous air does in some
degree. Priestley here refers to a mixture obtained by distilling
nitrates, which is essentially a mixture of nitric peroxide with
oxygen. A candle burns in such a mixture, depriving the nitric peroxide
of part of its oxygen, and converting it into nitric oxide mixed with
nitrogen. Nitric oxide, deprived of the excess of peroxide by shaking
with water, with which the peroxide reacts and is absorbed, is no
longer capable of supporting the combustion of a candle; and when added
to ordinary air it combines with its oxygen, again forming nitric
peroxide, which in its turn is absorbed by water.
Priestley’s experiments were performed at intervals from August 1774
till March 1775, and at that date it occurred to him to mix with
his dephlogisticated air some nitric oxide over water; absorption
took place, and he concluded that he might assume his new air to be
respirable. And what surprised him especially was, that even after
addition of nitric oxide and agitation with water, the residue still
supported the combustion of a candle. A mouse, too, lived half an
hour in the new air, and revived after being removed; whereas similar
experiments with an equal volume of common air had shown that, after
respiring it for a quarter of an hour, a mouse was indisputably dead.
Even after the mouse had breathed it for so long a time, it was still
capable of supporting the combustion of a candle; and this induced
him to add more nitric oxide to the respired air, when he found that
a further contraction occurred. He reintroduced the same unfortunate
mouse into the remainder of the air--a portion to which nitric oxide
had not been added--when it lived for another half-hour, and was quite
vigorous when withdrawn.
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