The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
“From the foregoing experiments it appears that when a mixture of
inflammable and dephlogisticated air is exploded in such proportion
that the burnt air is not much phlogisticated, the condensed liquor
contains a little acid, which is always of the nitrous kind,
whatever substance the dephlogisticated air is procured from; but
if the proportion be such that the burnt air is almost entirely
phlogisticated, the condensed liquor is not at all acid, but seems pure
water, without any addition whatever; and as, when they are mixed in
that proportion, very little air remains after the explosion, almost
the whole being condensed, it follows that almost the whole of the
inflammable and dephlogisticated air is converted into pure water.” The
quantity of uncombined gas was so small that it must be regarded as an
impurity. “There can be little doubt that it proceeds only from the
impurities mixed with the dephlogisticated and inflammable air, and
consequently that if those airs could be obtained perfectly pure, the
whole would be condensed.”
The next paragraph is interesting. “During the last summer also [of
1781] a friend of mine gave some account of them [these experiments]
to Mr. Lavoisier, as well as of the conclusion drawn from them, that
dephlogisticated air is only water deprived of phlogiston; but at
that time, so far was Mr. Lavoisier from thinking any such opinion
warranted, that, till he was prevailed upon to repeat the experiment
himself, he found some difficulty in believing that nearly the whole of
the two airs could be converted into water.”
And next comes an important deduction. “Phlogisticated air appears
to be nothing else than the nitrous acid united to phlogiston; for
when nitre is deflagrated with charcoal, the acid is almost entirely
converted into this kind of air.” This is the first statement of the
true relation between nitrogen and nitric acid; we should now state the
matter by the expression, “Nitrogen is nothing else than nitric acid
deprived of oxygen.” And the further deduction is made that “it is
well known that nitrous acid is also converted by phlogistication
into nitrous air, in which respect there seems a considerable analogy
between that and the vitriolic acid; for this acid, when united to a
smaller proportion of phlogiston, forms the volatile sulphurous acid
and vitriolic acid air, both of which, by exposure to the atmosphere,
lose their phlogiston, though not very fast, and are turned back
into the vitriolic acid; but when united to a greater proportion
of phlogiston, it forms sulphur, which shows no signs of acidity.”
“In like manner the nitrous acid, united to a certain quantity of
phlogiston, forms nitrous acid and nitrous air, which readily quit
their phlogiston to common air; but when united to a different, in
all probability a larger quantity, it forms phlogisticated air, which
shows no signs of acidity, and is still less disposed to part with its
phlogiston than sulphur.”
Public-domain text, read in full here on John Shaqi.
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