The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
Nothing has been said here regarding the rival claims of Watt to the
discovery of the composition of water, and little need be said. The
discovery was made by both in 1784, yet Cavendish visited Watt at
Birmingham in 1785, and was apparently on the best of terms with him;
and Watt, as proved by Cavendish’s diary, showed him many of his
devices connected with the steam-engine. There can be no doubt that
Watt had also discovered that when hydrogen and oxygen are exploded
together water is the sole product, but he coupled the phenomenon with
views involving the material nature of heat, or caloric, as it was then
called, which Cavendish repudiated.
Cavendish’s later work was carried out in a villa at Clapham, which
was fitted as a laboratory, workshop, and observatory, but he had
a town-house near the British Museum, at the corner of Gower Street
and Montague Place. He had also a library in Dean Street, Soho, which
was available for any scientific man who chose to present himself. So
singular were Cavendish’s habits that when he wished a book he went to
this house and borrowed it as from a public library, giving a receipt
for it.
Of all men, Cavendish was probably the most singular, but there can be
no question of his extraordinary genius.
[23] _Brit. Assoc. Report_, 1839, p. 64.
[24] _Experiments and Observations on Different Kinds of Air_, vol. i.
p. 181, and vol. ii. p. 238. Second edition, 1776.
CHAPTER V
THE DISCOVERY OF ARGON
With the advent of Lavoisier’s system of representing the phenomena
of combustion, and the expression in his terms of the various changes
resulting in air when metals are oxidised, and when carbonaceous
substances burn, the investigation of air was abandoned. It was no
longer regarded as a mysterious element, possessed of “chaotic”
properties, but was held to be a mixture of oxygen, nitrogen, and small
quantities of carbon dioxide and water vapour, together with a trace
of ammonia. More exact determinations of the proportion between its
oxygen and so-called nitrogen than Cavendish had made by the nitric
oxide method were carried out in 1804 by Gay-Lussac and Humboldt, by
explosion with measured quantities of hydrogen, according to the method
suggested by Volta; and they concluded, from a large number of analyses
made on specimens collected in all weathers and from various
localities, that 100 volumes of air contained 21 volumes of oxygen and
79 volumes of nitrogen. These experiments, too, led Gay-Lussac to the
conviction that oxygen and hydrogen unite to form water in the exact
proportion of one volume of the former to two volumes of the latter;
and he published, some years later, accounts of numerous experiments
of the same kind, as the result of which he found that, when two gases
combine or react with each other, they do so in some simple number of
volumes; for example, one to one, one to two, or one to three.
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