The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
But there still remained, in Cavendish’s opinion, one point unproved.
It was still conceivable that the potash might contain some
“inflammable matter” which would diminish the air on sparking, and
therefore oxygen nearly pure was sparked in presence of potash; but
only a very small diminution of volume occurred, owing probably to some
nitrogen present as an impurity in the oxygen. Water was substituted
for potash with the same result; but if litmus was added to the water
the colour was discharged, and lime-water introduced into the tube
gave a cloud, showing that “the litmus, if not burnt, was at least
decompounded, so as to lose entirely its purple colour and to yield
fixed air; so that, though soap-lees cannot be decompounded by the
process, yet the solution of litmus can, and so very likely might the
solutions of many other combustible substances.”
Such are the chemical researches of Cavendish. Of all experimenters
on the subject he was undoubtedly the greatest, though Mayow and
Scheele were near rivals. But his researches were so complete that it
is scarcely possible to criticise. He was not content with partial
results: every point was proved and re-proved, and every possibility
of erroneous conclusion was allowed for. It is curious that he did not
employ the balance to check his results. Had he done so he could not
have remained an adherent of the phlogistic theory. Although, as we
have seen, he was perfectly acquainted with the method in which his
results were interpreted by Lavoisier, he chose the old well-trodden
path leading to the wilderness of distorted facts. Lavoisier tried to
repeat Cavendish’s experiments, but without success; and in 1788 the
last part of his _Experiments on Air_ was published, in which he
recorded the successful repetition by a Committee of the Royal Society
of the conversion of nitrogen into nitric acid by the electric spark in
presence of oxygen and potash.
His remaining papers deal with meteorological and astronomical
subjects. One, published in 1790, refers to the height of a remarkable
aurora seen in 1784; another to the civil year of the Hindoos; and
another to a method for reducing lunar distances. And in 1798 his
famous memoir on the density of the earth appeared. It would be quite
beyond the province of this book to enter into any detail regarding
it; but it may be remarked in passing that the method consisted in
measuring, by means of a torsion balance, the attraction of one leaden
ball for another, and that recent experiments, made with the utmost
refinement, have barely altered the number which he obtained,
5·4, to 5·527.
His last paper, on an improvement in a machine for dividing
astronomical instruments, was published in 1809, the year before his
death.
Public-domain text, read in full here on John Shaqi.
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