The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
The gases can be almost entirely extracted by boiling the water. But to
boil large quantities of water at one operation in a vessel suitable
for collecting the escaping gas is not easy. It is much simpler to
cause the water to pass slowly through a can below which there is a
powerful flame, so that the water in its passage becomes heated to
the boiling-point, and gives off its gas before it escapes. Of course
the gas collected contained oxygen, but this was easily removed by
the usual method of passing it over red-hot copper. The density of
the residual gas was determined, and it was found to be at least as
much greater than that of “atmospheric” nitrogen as the density of
“atmospheric” nitrogen exceeded that from chemical sources. Hence it
was to be concluded that the new constituent of air, argon, was being
concentrated by dissolving air in water, and extracting the dissolved
mixture of gases. A third proof that argon exists in air will be given
farther on.
[Illustration: FIG. 3.]
In order that the properties of the newly-discovered gas, argon, might
be thoroughly investigated, it was necessary to prepare it on a much
larger scale than had hitherto been attempted, and this was carried out
by the two processes for removing the oxygen and nitrogen which have
been already described. Supposing the new gas to have the density 20
compared with oxygen as 16, the density of the atmospheric mixture of
nitrogen and argon compared with that of nitrogen alone shows that air
should, roughly speaking, contain less than one part of argon in one
hundred. Hence, to obtain a litre of argon, it was necessary to work up
a large quantity of atmospheric nitrogen. Now, as has just been said,
there are two ways of doing this. (1) One is to produce an electric
flame between two pieces of stout platinum in air, confined in a large
glass balloon of about 6 litres capacity, over a weak solution of
caustic soda. For this purpose a very powerful rapidly alternating
current is necessary. The latest, and apparently the best, method
of carrying this out, was described by Lord Rayleigh in his Royal
Institution lecture in January 1896. The neck of the balloon is placed
downwards, and connected by means of a glass tube, passing through
a cork which closes the neck, with a rotating fan or paddle-wheel
with curved blades, which forces through the tube a weak solution of
caustic soda; another tube, also entering through the cork, conveys
away the excess of soda to the fan, whence it is again forced into
the balloon. The soda solution makes a fountain in the balloon, and
flows in a uniform stream down its sides, covering its inner surface
with a thin layer of liquid. Through the cork the two electrodes,
with their thick platinum terminals, enter; and there is another tube
besides, which conveys into the balloon a mixture of air and oxygen
in such proportions that they combine completely on exposure to the
flame. The layer of soda solution plays a double part. It prevents the
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