The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
undue heating of the glass balloon, which otherwise must be sunk in
running water in order to keep it cool; and it exposes a very large
and constantly renewed surface of soda to the nitrous fumes which are
produced by the combination of the nitrogen and the oxygen, and so
removes them as quickly as they are formed. It appears probable that
the union results initially in the formation of nitric oxide, NO, which
then unites partially with oxygen to form some nitrogen peroxide,
NO_{2}. This is absorbed by the soda, giving a mixture of nitrite and
nitrate of sodium, NaNO_{2} and NaNO_{3}. Working in this way, from 7
to 8 litres of mixed gases can be made to combine per hour. The rapidly
alternating current is best obtained by the use of a transformer; and
as the heating effect on the platinum terminals is very great, they
must be made of stout rods.
(2) To prepare a large quantity of argon by the absorption of
atmospheric nitrogen by magnesium is a somewhat tedious process.
The air must be first freed from oxygen by means of red-hot copper,
and the atmospheric nitrogen collected in a gasholder. Long tubes
of combustion-glass tubing, which stands a bright red heat without
becoming deformed, are packed with magnesium turnings and heated to
redness in long gas furnaces, such as are used in organic analyses;
and through these the “atmospheric nitrogen,” dried by passage over
soda-lime and phosphorus pentoxide, is then passed. The magnesium
begins to glow at that end of the tube nearest the entrance, owing to
its combination with nitrogen, and a hot ring is seen to travel
slowly down the tube to the other end, marking the place where such
combustion is in progress. The gas issuing from the tube is collected
in a small gasholder. When one tube of magnesium is exhausted, another
is substituted for it. Each tube is capable of absorbing about seven
litres of nitrogen, so that to obtain a litre of argon about one
hundred litres of “atmospheric nitrogen” must be employed, and about
fourteen tubes of magnesium are required. M. Maquenne, who has prepared
the nitrides of several metals, has stated that a mixture of lime and
magnesium, yielding metallic calcium, is more easily manipulated than
pure magnesium, owing to the absorption of the nitrogen at a lower
temperature. The process has not been tried on a large scale, but if
the temperature of combination of magnesium and nitrogen could be thus
reduced, it would much facilitate the operation, for the greatest care
has to be taken not to overheat the combustion tube, else it softens,
and blows into holes. Porcelain tubes are attacked by the magnesium,
and crack on cooling; and iron tubes are difficult to clean out.
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