The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
But these experiments lead to a further result. They show that
nitrogen, procured from its compounds, when treated in the same way as
atmospheric nitrogen, yields no trace of argon. And it must therefore
be taken as proved without doubt that argon is actually present in the
atmosphere as such, and is not produced by any process to which the
nitrogen has been submitted in order to extract it.
This point having been settled, the actual percentage of argon in
atmospheric air next invited inquiry. It is by no means very easy to
absorb quantitatively the whole of the nitrogen from an accurately
measured sample of air, for small gains and losses are apt to occur.
It is necessary to keep the air out of contact with water as much as
possible, because argon, being more soluble than nitrogen, dissolves
in larger proportional amount in the water, and is thereby partially
removed. The air was therefore entirely manipulated over mercury. The
processes were like those previously employed: most of the nitrogen was
removed with magnesium, and the residue was freed from all nitrogen by
sparking with oxygen. Experiments directed to this end were carried
out by Mr. Kellas in Professor Ramsay’s laboratory, and independently
by M. H. Schloesing in Paris. The results were identical. “Atmospheric
nitrogen” consists of pure nitrogen mixed with 1·186 per cent of its
volume of argon.
It is now possible, knowing the percentage of argon in atmospheric
nitrogen and its density (19·94), to calculate whether Lord Rayleigh’s
determinations of the density of atmospheric nitrogen were correct.
The weight of one litre of pure nitrogen is 1·2511 gram, and of argon,
1·7818 gram; hence a litre of a mixture of 98·814 volumes of nitrogen
with 1·186 volume of argon must possess the weight 1·2574 gram. The
actual number found by Lord Rayleigh was 1·2572 gram, which is almost
exactly identical with the number calculated.
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