The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
Mineral waters, as a rule, contain small quantities of argon mixed
with oxygen, nitrogen, carbon dioxide, and in some cases sulphuretted
hydrogen and helium, a gas of which more hereafter. The waters actually
examined were the Bath waters, which contain much nitrogen, a little
argon, and a trace of helium; the Buxton waters, containing nitrogen
and a little argon; the water from “Allhusen’s Well,” Middlesborough,
which evolved gas of an inflammable nature consisting mainly of
nitrogen, but also containing marsh-gas, and argon to the extent
of O·4 per cent; water from boiling springs in Iceland evolved gas
containing somewhat more argon than air does, viz. 1·14 per cent; and
lastly, water from the Harrogate sulphur springs yielded a gas largely
consisting of a mixture of sulphuretted hydrogen, carbon dioxide
and nitrogen, but giving also an appreciable amount of argon. Such
determinations show that argon is not merely confined to the atmosphere
above the earth, but that it penetrates the earth and is contained in
subterraneous water. These results have been obtained by Lord Rayleigh,
Professor Ramsay, Mr. Travers, and Mr. Kellas.[26]
Similar experiments have been made by Dr. Bouchard in Paris[27] on
effervescing waters from Cauterets in the Pyrenees. One of those
springs yielded a mixture of nitrogen with a small amount of argon
and helium; another yielded only nitrogen and argon; while a third
gave nitrogen and helium. Such are, up to the present, the sources
of argon. It has been several times stated that the element helium,
which is closely allied to argon in its physical properties, and in
its inertness, is a normal constituent of our atmosphere, although in
very small amount. This, however, is not the case. For the argon of the
atmosphere has been very carefully examined for helium in two ways.
First, Lord Rayleigh dissolved a large quantity of argon in water,
leaving only a minute bubble undissolved. Now while 1000 parts of water
dissolve 40 parts of argon, they dissolve only 7 parts of helium; and
if helium were present, it should be found in the residue. But careful
spectroscopic examination failed to reveal the characteristic lines
of helium. Next, Professor Ramsay and Dr. Collie diffused argon
fractionally; and as the densities of argon and helium are very
different (2 and 20), the helium should have been visible in the
first portion which diffused. There was no trace to be detected.
But, further, they submitted this portion of argon to a discharge of
electricity for several hours in a vacuum-tube provided with platinum
electrodes. This process, as they proved, carries out the helium
with the platinum which is splashed on to the sides of the tube. The
argon was then removed by pumping it off in the cold. On heating the
splashed-off platinum, no helium spectrum could be observed. In a
similar experiment, in which a very minute trace of helium had been
added to the argon, there was no difficulty in detecting the helium on
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account