The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
heating the tube. The conclusion therefore follows that no helium is
present in our atmosphere.
It is, besides, exceedingly improbable that helium should be present.
For, as shown by Dr. Johnstone Stoney, the rate of motion of a molecule
of hydrogen is so rapid that, on finding its way to the confines of the
atmosphere, it would escape, and travel through space until it found a
planet of sufficient attractive force to hold it. The same is true of
helium. Were helium present in the atmosphere, it would ultimately
leave us for the sun, or for some planet of much greater mass than the
earth. This conception of Dr. Stoney’s tallies with the observation
that the moon, a planet of small mass, is devoid of an atmosphere, and
that the sun, a body with a mass 300,000 times as great as the earth,
shows in its chromosphere the spectra both of hydrogen and of helium
with great brilliancy.
It is now of interest to inquire what are the properties of argon and
how it is related to other elements.
[25] _Proc. Roy. Soc._ vol. liii. p. 134.
[26] _Proc. Roy. Soc._ vol. lix. p. 68.
_Phil. Trans._ vol. clxxxvi. p. 227.
[27] _Compt. rend._ vol. cxxi. p. 394.
CHAPTER VI
THE PROPERTIES OF ARGON
The density of a gas is one of its most characteristic and important
properties. Avogadro’s law, which postulates that equal volumes of
gases, at equal temperature and pressure, contain equal numbers of
molecules, renders it possible to compare the weights of the molecules
by determining the relative weights of the gases. Thus, as the ratio
between the densities of nitrogen and oxygen is 7 to 8, a single
molecule of nitrogen, the smallest portion which can exist in freedom,
uncombined with other elements, is ⅞ths of the weight of a single
molecule of oxygen. Hence a determination of the density of argon leads
directly to a knowledge of the relative weight of a single molecule of
this gas.
But with what should the density of argon be compared? What gas must
serve as the standard of density? To answer this question, it is
necessary to give a short sketch of the development of chemical theory
regarding the atomic weights of elements and their relative volumes.
Dalton proposed to adopt as the unit of atomic weight the weight of the
lightest atom, namely, that of hydrogen. Taking, for example, water as
one substance containing hydrogen, its percentage composition by weight
is--
Hydrogen 11·11 per cent
Oxygen 88·88 "
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