The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
These difficulties may, however, be easily overcome by the following
supposition, which was first formulated by Avogadro in 1811. The
ordinary particles of hydrogen and of oxygen are complex, each
containing at least two atoms, or smaller particles, which usually
exist in combination with each other, or with atoms of some other
element. Two volumes of hydrogen, therefore, contain twice as many
particles as one volume of oxygen; to such particles the name
“molecules” is now universally applied. And as these molecules are
themselves each made up of two smaller particles, now termed “atoms,”
there exist in two volumes of hydrogen twice as many atoms as in one
volume of oxygen. On combination, the atoms in the molecules of
hydrogen and oxygen rearrange themselves, so that two atoms of hydrogen
and one atom of oxygen combine to form a molecule of water-vapour,
containing three atoms. The steam now contains as many molecules as did
the hydrogen before combination; but whereas the molecules of hydrogen
originally consisted of two atoms each, the molecules of steam contain
three atoms. It is this which causes the contraction from three volumes
to two when hydrogen and oxygen molecules exchange partners in forming
water molecules.
Of course the difficulty would meet with an equally good explanation if
it were supposed that the hydrogen molecules and the oxygen molecules
each contained four atoms, or eight atoms; but there is no need to
increase the complexity of the molecule, and the assumption that
these molecules are “diatomic” completely serves the purpose. The
composition of water is therefore believed to be two atoms of hydrogen
in combination with one atom of oxygen; and when hydrogen and oxygen
unite to form water, a transaction similar to an exchange of partners
is supposed to occur; the atoms of hydrogen and oxygen are imagined to
leave their partners of like kind, and to rearrange themselves so that
groups of atoms, or molecules, each containing two atoms of hydrogen
and one of oxygen, are formed. To such an arrangement the formula
H_{2}O is applied, while ordinary hydrogen molecules may be represented
as H_{2}, and molecules of oxygen as O_{2}.
It has been shown already (p. 150) how Lord Rayleigh obtained the
number 15·882 for the density of oxygen compared with that of hydrogen.
To determine the atomic weights of elements, the usual process has been
to analyse their oxides, for only a few elements form compounds with
hydrogen. Thus the analysis of copper oxide yields the numbers--
Copper 79·96 per cent
Oxygen 20·04 "
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