The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
And as no compound of copper and hydrogen is known which lends itself
to analysis, the atomic weight of copper is necessarily referred to
that of oxygen. If the atomic weight of hydrogen be taken as unity,
that of oxygen, from Lord Rayleigh’s determination, must be 15·882,
because, in comparing the weights of equal volumes of the gases, a
comparison is made of the weights of equal numbers of molecules; and as
it is reasonable to suppose that each molecule of hydrogen and of
oxygen contains two atoms, the number 15·882 represents the weight of
an atom of oxygen compared with that of an atom of hydrogen taken as 1.
But this number has not been regarded as sufficiently established by
experiment. Other observers (for the importance of this ratio has been
acknowledged since the beginning of the century) have obtained results
differing from that given above, although not to any great extent. And
as it is a matter of indifference what basis or standard be taken for
atomic weights, which represent only relative numbers, it is common
to accept the atomic weight of oxygen as 16, in which case that of
hydrogen, if Lord Rayleigh’s determination of its density be regarded
as accurate, would be 1·0074. Hence if we place the atomic weight of
oxygen as 16, that of copper would be 63·34. And as with copper, so
with most other elements. It is very seldom that the atomic weight of
an element has been directly compared with that of hydrogen; it is, in
fact, almost always ascertained by analysis of its chloride, bromide,
or oxide; and the atomic weights of chlorine and bromine have been very
carefully compared with that of oxygen. There is, besides, another
convenience in accepting 16 as the atomic weight of oxygen: it is that
many atomic weights are then represented by whole numbers instead of by
fractions; thus, sulphur has the atomic weight 32, if oxygen be made
16, whereas, if it were 15·882, the atomic weight of sulphur would be
31·764, a number much more difficult to remember.
We see then that it is convenient to refer the density of argon
to oxygen taken as 16. The density obtained by Professor Ramsay
in February 1895, using a globe of small capacity (only 160 cubic
centimetres), was 19·94; exactly the same result was given by Lord
Rayleigh’s experiments in June 1895 on argon prepared by means of the
electric discharge, with a balloon of much greater capacity, which
held over two litres of gas. Now as a molecule of oxygen consists of
two atoms, the weight of a molecule is twice the atomic weight, or 32;
and as a given volume of argon must contain as many molecules as the
same volume of oxygen, the weight of a molecule of argon must be twice
19·94, or 39·88.
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