The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
It was discovered by Dulong and Petit, early in the century, that the
higher the atomic weight of an element the less heat is required to
raise its temperature through a given number of degrees. This heat can
be measured by dropping a fragment of the element, carefully weighed
and heated to a known temperature, into a known weight of cold water,
and ascertaining what rise of temperature the water undergoes, owing to
the heat communicated to it by the element. These comparative amounts
of heat, if water is chosen as the standard, are termed specific heats.
And as the specific heats of elements have been found by experiment
to be inversely as their atomic weights, the product of the specific
heat of any element and its atomic weight will give a constant number.
If the quantity of element weighed is one gram, and its rise of
temperature one degree, the numerical value of this product is
about 6·4.
Now the specific heat of mercury has been found to equal 0·032; that
is to say, it requires only a fraction of the value of 0·032 of heat
to raise the temperature of say 1 gram of mercury through one degree,
whereas the amount of heat necessary to raise 1 gram of water through
one degree is represented by the number 1. Hence this number, 0·032,
multiplied by the atomic weight of mercury, should yield the product
6·4; and it is seen at once that that number must be 200, for 200 ×
0·032 = 6·4. This is an additional reason for believing that the atomic
weight of mercury must be represented by the number 200.
We come next to a confirmatory piece of evidence which greatly
strengthens the view that the atomic weight of mercury must be 200;
but before entering into detail let us see what an atomic weight of
200 involves. The density of mercury gas is 100, and its molecular
weight must be 200. But if its atomic weight is also 200, it follows of
necessity that its molecule and its atom must be identical; that unlike
oxygen and hydrogen, its molecule consists, not of two atoms, but of
one single atom. There is nothing strange in this conclusion; there is
no evident reason why single atoms should not act as molecules, or
independent particles, able to exist in a free state, uncombined with
each other or with any other molecules.
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