The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
The specific heat of a gas is measured in much the same manner as
that of a solid. A known volume of the gas is caused to pass through
a spiral tube, heated to a certain definite high temperature; it then
enters a vessel containing a known weight of water, traverses a spiral
tube immersed in the water, and parts with its heat to the water.
Knowing, therefore, the weight of the gas and its initial temperature,
and also the rise of temperature of the water, the specific heat of
the gas can be compared with that required to raise an equal weight of
water through one degree. But gases are found to possess two specific
heats. If the volume of the gas is kept constant, so that the gas does
not contract during its loss of heat, one number for its specific heat
is obtained; while if it is allowed to alter its volume a higher figure
represents its specific heat. It will be necessary to consider the
cause of this difference, in order to understand what conclusions can
be drawn respecting the molecular nature of argon from a determination
of the ratio between its two specific heats--that at constant pressure
and that at constant volume.
If a gas is allowed to expand into a vertical cylinder so as to drive
up a piston loaded with a weight, it is said to “do work.” The work
is measured by the weight on the piston, and also by the height to
which it is raised. Thus, if the weight is one pound, and the height
one foot, one foot-pound of work is done; if the mass is one gram and
the height one centimetre, one gram-centimetre of work is done. During
this process the gas must expand; and if it were enclosed in some
form of casing through which heat could not pass--we know of no such
casing, but we can contrive casings through which heat passes very
slowly--the temperature of the gas would fall during its expansion, and
it would lose heat. For each loss of one heat-unit or calory--_i.e._
the amount of heat given off by 1 gram of water in cooling through 1°
Centigrade--the gas would perform 42,380 gram-centimetres of work; it
would raise a weight of nearly 4¼ kilograms, or about 9⅓ lbs.,
through 1 centimetre, or nearly half an inch.
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