The Growth of a Crystal: Being the eighteenth Robert Boyle lecture — John Shaqi
The Growth of a Crystal: Being the eighteenth Robert Boyle lectureMiers, Henry Alex
Science
The Growth of a Crystal: Being the eighteenth Robert Boyle lecture
Miers, Henry Alex
Crystallography
I need not weary this audience with any description of these
experiments, which doubtless seem more interesting and important to
their author than to anyone else. But I wish to draw your attention to
the result that came out of them. I found that it was possible with the
same apparatus to measure the refractive power of the liquid in absolute
contact with the growing crystal and from this to calculate the exact
strength of the solution at that spot. It was thus possible to prove
that the solution in contact with the crystal is rather stronger than at
a very short distance from it, and to know exactly how much stronger. In
other words, while a crystal of, say, alum is growing, the liquid in
contact with it contains more particles of alum and less particles of
water, or is richer in alum, than the liquid at a short distance from
it. I will ask you to bear this in mind in what follows. There is
another curious fact connected with this subject. Crystals of nitrate of
soda have almost exactly the same shape and almost the same physical
properties as crystals of the common mineral calcite, which, in its
purest and most perfect form of transparent glassy crystals, is known as
Iceland spar. Now, when a perfectly clean crystal of Iceland spar is
immersed in a strong solution of nitrate of soda, although it is not
dissolved by the liquid itself and therefore cannot crystallize out of
it, the Iceland spar actually continues to grow, and becomes enveloped
by the nitrate of soda so as to form what is apparently a single
crystal.
It appears, therefore, highly probable that a crystal of nitrate of soda
and a crystal of Iceland spar behave alike in this respect when placed
in a strong solution of the nitrate; each draws to itself the liquid
nitrate in the solution, then draws it out of the solution in the solid
state, and further arranges the particles upon its own surface in a
perfectly regular manner, so that the arrangement of the particles in
the shell of nitrate is the same as the arrangement of the particles in
the spar which it surrounds; just as a bricklayer sets upon the rising
wall new bricks arranged in the same way as those which he has already
laid. I remember that on LORD KELVIN’S last visit to Oxford, shortly
before his death, mindful of his BOYLE Lecture, I showed him, in company
with my pupil, Mr. BARKER, this beautiful experiment, with which he was
at that time not familiar, and I shall never forget the interest and
enthusiasm with which he witnessed the beautifully regular and
instantaneous growth of the nitrate crystals. He always was as
enthusiastic and inquiring as a boy, and these characteristics were
exhibited on that occasion in his old age. It is an experiment which
sets one thinking, and I have no doubt that, if LORD KELVIN, even at
that advanced age, had set his mind to consider it, he would have been
able to deduce far more than it has yet suggested to those who have
witnessed it.[3]
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