The Growth of a Crystal: Being the eighteenth Robert Boyle lectureMiers, Henry Alex
Science
The Growth of a Crystal: Being the eighteenth Robert Boyle lecture
Miers, Henry Alex
Crystallography
One is naturally led to imagine that before any solution begins to
crystallize in the solid form it passes into this liquid state, and that
the particles have begun to set themselves and all to face the same way
before they begin to cohere and to build themselves into a solid. But so
far as I know there is no evidence in favour of this suggestion—a
solution before solid crystals begin to appear does not behave like a
liquid crystal, but remains an ordinary solution up to the last moment
when new crystals are born in it or are started by inoculation with a
crystal germ.
The other discovery, which is in the nature of a speculation, is that of
another person whom I am proud to reckon among my former pupils, namely,
Professor POPE of Cambridge, working in conjunction with Mr. BARLOW. Mr.
BARLOW had already been referred to by LORD KELVIN in his BOYLE Lecture
as the author of ingenious researches upon the various ways in which
materials can be packed together, and the different arrangements and
structures which result from this packing.
These two workers have now propounded a theory according to which, if
the various atoms which constitute a substance are represented by
spheres whose sizes represent the valency of the atoms, and if these
spheres are packed together as closely as they will go, the resulting
structure will represent very nearly the structure of the crystal; and
so it may be possible for the first time from a knowledge of the
chemical constitution of a substance to predict the structure of its
crystals and therefore the form in which it will crystallize. You
remember the bee’s cell arrangement and the similar arrangement of balls
got by placing a ball in each cell and then removing the cells. Another
way of getting the same arrangement is to place a number of equal balls
on a table and to squeeze them together until they are packed as closely
as possible. This arrangement of closest packing, the arrangement of a
pyramid of cannon-balls, is precisely the same as before, the one in
which each ball on the table is in contact with six others. According to
POPE and BARLOW the atoms in a crystal simply pack themselves together
as closely as possible, but instead of being equal in size they have
generally to be represented as of different sizes according to their
valencies. If we imagine the coalescence of atoms to form a crystal to
be due to their mutual attraction, it is very reasonable to suppose that
they will get as close together as is possible, and therefore that the
ways of close packing are the ways of crystal structure. The theory
therefore suggests a reason for the growth as well as for the shape of a
crystal. I may remind you that the bee’s cell itself, which is in the
world of life the thing that most nearly resembles crystalline
structure, is due to this same principle of close packing; for in their
efforts to get as closely together as possible the bees are constrained
to get into the hexagonal arrangement.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account