The handbook of soap manufactureSimmons, W. H. (William Herbert)
Science
The handbook of soap manufacture
Simmons, W. H. (William Herbert)
Soap
French and Dalmatian.--Specific gravity at 15 deg. C., 0.900-0.916; optical
rotation, usually dextro-rotatory, up to +15 deg., but may occasionally be
laevo-rotatory, especially if stalks have been distilled with the leaves;
ester, calculated as bornyl acetate, 1-6 per cent.; total borneol, 12-18
per cent.; usually soluble in 1-2 volumes of 82.5 per cent. alcohol.
Spanish.--The properties of the Spanish oil are similar to the others,
except that it is more frequently laevo-rotatory.
Rosemary oil contains pinene, camphene, cineol, borneol, and camphor.
_Sandalwood oil_, obtained by distillation of the wood of Santalum album
(East Indian), Santalum cygnorum (West Australian), and Amyris
balsamifera (West Indian). The oils obtained from these three different
sources differ very considerably in value, the East Indian being by far
the best.
East Indian.--Specific gravity at 15 deg. C., 0.975-0.980; optical rotation,
-14 deg. to -20 deg.; refractive index at 20 deg. C., 1.5045-1.5060; santalol,
92-97 per cent.; usually soluble in 4-6 volumes of 70 per cent. alcohol,
though, an old oil occasionally is insoluble in 70 per cent. alcohol.
West Australian.--Specific gravity at 15 deg. C., 0.950-0.968; optical
rotation, +5 deg. to +7 deg.; alcohols, calculated as santalol, 73-75 per cent.;
insoluble in 70 per cent. alcohol, but readily dissolves in 1-2 volumes
of 80 per cent. alcohol.
West Indian.--Specific gravity at 15 deg. C., 0.948-0.967; optical rotation,
+13 deg. 30' to +30 deg.; insoluble in 70 per cent. alcohol.
In addition to free santalol, the oil contains esters of santalol and
santalal.
_Sassafras oil_, distilled from the bark of Sassafras officinalis, and
obtained chiefly from America. Specific gravity at 15 deg. C., 1.06-1.08;
optical rotation, +1 deg. 50' to +4 deg.; refractive index at 20 deg. C.,
1.524-1.532; soluble in, 6-10 volumes of 85 per cent. alcohol,
frequently soluble in 10-15 volumes of 80 per cent. alcohol.
The chief constituents are safrol, pinene, eugenol, camphor, and
phellandrene. The removal of safrol, either intentionally or by
accident, owing to cooling of the oil and consequent deposition of the
safrol, is readily detected by the reduction of the specific gravity
below 1.06.
_Thyme oil, red and white_, distilled from the green or dried herb,
Thymus vulgaris, both French and Spanish oils being met with. These oils
are entirely different in character.
French.--Specific gravity at 15 deg. C., 0.91-0.933; slightly laevo-rotatory
up to -4 deg., but usually too dark to observe; phenols, by absorption with
10 per cent. aqueous caustic potash, 25-55 per cent.; refractive index
at 20 deg. C., 1.490-1.500; soluble in 1-1.5 volumes of 80 per cent.
alcohol.
Spanish.--Specific gravity at 15 deg. C., 0.955-0.966; optical rotation,
slightly laevo-gyrate; phenols, 70-80 per cent.; refractive index at 20 deg.
C.; 1.5088-1.5122; soluble in 2-3 volumes of 70 per cent. alcohol.
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