The handbook of soap manufactureSimmons, W. H. (William Herbert)
Science
The handbook of soap manufacture
Simmons, W. H. (William Herbert)
Soap
In addition to the phenols, thymol or carvacrol, these oils contain
cymene, thymene and pinene.
The white thyme oil is produced by rectifying the red oil, which is
generally effected at the expense of a considerable reduction in phenol
content, and hence in real odour value of the oil.
_Verbena Oil._--The oil usually sold under this name is really
lemon-grass oil (which see _supra_). The true verbena oil or French
verveine is, however, occasionally met with. This is distilled in France
from the verbena officinalis, and has the following properties: Specific
gravity at 15 deg. C., 0.891-0.898; optical rotation, slightly dextro- or
laevo-rotatory; aldehydes, 70-75 per cent.; soluble in 2 volumes of 70
per cent. alcohol.
The oil contains citral.
_Vetivert oil_, distilled from the grass, Andropogon muricatus, or Cus
Cus, and grown in the East Indies.
Specific gravity at 15 deg. C., 1.01-1.03; optical rotation, +20 deg. to +26 deg.;
saponification number, 15-30; refractive index at 20 deg. C., 1.521-1.524;
soluble in 2 volumes of 80 per cent. alcohol.
The price of this oil makes its use prohibitive except in the highest
class soaps.
_Wintergreen Oil._--There are two natural sources of this oil, the
Gaultheria procumbens and the Betula lenta. Both oils consist almost
entirely of methyl salicylate and are practically identical in
properties, the chief difference being that the former has a slight
laevo-rotation, while the latter is inactive.
Specific gravity at 15 deg. C., 1.180-1.187; optical rotation, Gaultheria
oil, up to -1 deg., Betula oil, inactive; ester as methyl salicylate, at
least 98 per cent.; refractive index at 20 deg. C., 1.5354-1.5364; soluble
in 2-6 volumes of 70 per cent. alcohol.
Besides methyl salicylate, the oil contains triaconitane, an aldehyde or
ketone, and an alcohol.
_Ylang-ylang oil_, distilled from the flowers of Cananga odorata, the
chief sources being the Philippine Islands and Java. Specific gravity at
15 deg. C., 0.924-0.950; optical rotation, -30 deg. to -60 deg., and occasionally
higher; refractive index at 20 deg. C., 1.496-1.512; ester, calculated as
linalyl benzoate, 27-45 per cent., occasionally up to 50 per cent.;
usually soluble in 1/2 volume of 90 per cent. alcohol.
The composition of the oil is qualitatively the same as that of Cananga
oil, but it is considerably more expensive and therefore can only be
used in the highest grade soaps.
_Artificial and Synthetic Perfumes._
During the past few years the constitution of essential oils has been
studied by a considerable number of chemists, and the composition of
many oils has been so fully determined that very good imitations can
often be made at cheaper prices than those of the genuine oils,
rendering it possible to produce cheap soaps having perfumes which were
formerly only possible in the more expensive article.
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