The handbook of soap manufactureSimmons, W. H. (William Herbert)
Science
The handbook of soap manufacture
Simmons, W. H. (William Herbert)
Soap
An important adulterant, which should always be tested for, is
acetanilide (antifebrin), which may be detected by the characteristic
isocyanide odour produced when musk containing this substance is boiled
with alcoholic potash, and a few drops of chloroform added. Acetanilide
also increases the solubility in 95 per cent. alcohol.
_Neroli Oil (Artificial)._--Like jasmine oil, the chemistry of neroli
oil is now very fully known, and it is therefore possible to prepare an
artificial product which is a very good approximation to the natural
oil, and many such are now on the market, which, on account of their
comparative cheapness, commend themselves to the soap-perfumer. These
consist chiefly of linalol, geraniol, linalyl acetate, methyl
anthranilate, and citral.
_Mirbane Oil_ or _Nitrobenzene._--This is a cheap substitute for oil of
bitter almonds, or benzaldehyde, and is a very coarse, irritating
perfume, only suitable for use in the very cheapest soaps. It is
prepared by the action of a mixture of nitric and sulphuric acids on
benzene at a temperature not exceeding 40 deg. C. Its specific gravity is
1.205-1.206; refractive index at 20 deg. C., 1.550; and boiling point, 206 deg.
C.
_Niobe oil_, or _ethyl benzoate_, the ester obtained from ethyl alcohol
and benzoic acid, and having the specific gravity at 15 deg. C.,
1.094-1.095; refractive index at 20 deg. C., 1.5167; boiling point,
196.5 deg.-198 deg. C.; soluble in 1.5 volumes of 70 per cent. alcohol.
_Oeillet_ is a combination possessed of a sweet carnation-like odour and
having as a basis, eugenol or isoeugenol. Its properties vary with the
source of supply.
_Rose Oil (Artificial)._--Several good and fairly cheap artificial rose
oils are now obtainable, consisting chiefly of citronellol, geraniol,
linalol, phenyl ethyl alcohol, and citral. In some cases stearopten or
other wax is added, to render the oil more similar in appearance to the
natural article, but as these are inodorous, no advantage is gained in
this way, and there is, further, the inconvenience in cold weather of
having to first melt the oil before use.
_Safrol_, an ether which is the chief constituent of sassafras oil, and
also found in considerable quantity in camphor oil. It is sold as an
artificial sassafras oil, and is very much used in perfuming cheap
toilet or household soaps. Its specific gravity at 15 deg. C. is
1.103-1.106; refractive index at 20 deg. C., 1.5373; and it dissolves in
fifteen volumes of 80 per cent. alcohol.
_Santalol_, the alcohol or mixture of alcohols obtained from sandalwood
oil. Its specific gravity at 15 deg. C. is 0.9795; optical rotation, -18 deg.;
and refractive index at 20 deg. C., 1.507.
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