The handbook of soap manufactureSimmons, W. H. (William Herbert)
Science
The handbook of soap manufacture
Simmons, W. H. (William Herbert)
Soap
_Terebene_, a mixture of dipentene and other hydrocarbons prepared from
turpentine oil by treatment with concentrated sulphuric acid, is used
chiefly in medicated soaps. Its specific gravity at 15 deg. C. is
0.862-0.868; the oil is frequently slightly dextro- or laevo-rotatory;
the refractive index at 20 deg. C., 1.470-1.478.
_Terpineol_, an alcohol also prepared from turpentine oil by the action
of sulphuric acid, terpene hydrate being formed as an intermediate
substance. It has a distinctly characteristic lilac odour, and on
account of its cheapness is much used in soap perfumery, especially for
a lilac or lily soap. Its specific gravity at 15 deg. C. is 0.936-0.940;
refractive index at 20 deg. C., 1.4812-1.4835; and boiling point about
210 deg.-212 deg. C. It is optically inactive, and readily soluble in 1.5
volumes of 70 per cent. alcohol.
_Vanillin_, a white crystalline solid, melting at 80 deg.-82 deg. C. and
prepared by the oxidation of isoeugenol. It has a strong characteristic
odour, and occurs, associated with traces of benzoic acid and
heliotropin, in the vanilla bean. It can only be used in small quantity
in light-coloured soaps, as it quickly tends to darken the colour of the
soap.
CHAPTER IX.
GLYCERINE MANUFACTURE AND PURIFICATION.
_Treatment of Lyes--Evaporation to Crude
Glycerine--Distillation--Distilled and Dynamite
Glycerine--Chemically Pure Glycerine--Animal Charcoal for
Decolorisation--Glycerine obtained by other Methods of
Saponification--Yield of Glycerine from Fats and Oils._
As pointed out in Chapter II. the fatty acids, which, combined with soda
or potash, form soap, occur in nature almost invariably in the form of
glycerides, _i.e._, compounds of fatty acids with glycerol, and as the
result of saponification of a fat or oil glycerine is set free.
In Chapter V. processes of soap-making are described in which (1) the
glycerine is retained in the finished soap, and (2) the glycerine is
contained in the lyes, in very dilute solution, contaminated with salt
and other impurities. These lyes, though now constituting the chief
source of profit in the manufacture of cheap soaps, were till early in
last century simply run down the drains as waste liquor.
Much attention has been devoted to the purification and concentration of
glycerine lyes; and elaborate plant of various forms has been devised
for the purpose.
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