The handbook of soap manufactureSimmons, W. H. (William Herbert)
Science
The handbook of soap manufacture
Simmons, W. H. (William Herbert)
Soap
H. Jackson has, however, recently patented (Eng. Pat. 6,712, 1906) the
use of ammonium oleate for laundry work. This detergent is prepared in
the wash-tub at the time of use, and it is claimed that goods are
cleansed by merely immersing them in this solution for a short time and
rinsing in fresh water.
Neither of the definitions given above includes the sodium and potassium
salts of rosin, commonly called rosin soap, for the acid constituents of
rosin have been shown to be aromatic, but in view of the analogous
properties of these resinates to true soap, they are generally regarded
as legitimate constituents of soap, having been used in Great Britain
since 1827, and receiving legislative sanction in Holland in 1875.
Other definitions of soap have been given, based not upon its
composition, but upon its properties, among which may be mentioned that
of Kingzett, who says that "Soap, considered commercially, is a body
which on treatment with water liberates alkali," and that of Nuttall,
who defines soap as "an alkaline or unctuous substance used in washing
and cleansing".
_Properties of Soap._--Both soda and potash soaps are readily soluble in
either alcohol or hot water. In cold water they dissolve more slowly,
and owing to slight decomposition, due to hydrolysis (_vide infra_), the
solution becomes distinctly turbid. Sodium oleate is peculiar in not
undergoing hydrolysis except in very dilute solution and at a low
temperature. On cooling a hot soap solution, a jelly of more or less
firm consistence results, a property possessed by colloidal bodies, such
as starch and gelatine, in contradistinction to substances which under
the same conditions deposit crystals, due to diminished solubility of
the salt at a lower temperature.
Krafft (_Journ. Soc. Chem. Ind._, 1896, 206, 601; 1899, 691; and 1902,
1301) and his collaborators, Wiglow, Strutz and Funcke, have
investigated this property of soap solutions very fully, the researches
extending over several years. In the light of their more recent work,
the molecules, or definite aggregates of molecules, of solutions which
become gelatinous on cooling move much more slowly than the molecules in
the formation of a crystal, but there is a definite structure, although
arranged differently to that of a crystal. In the case of soda soaps the
colloidal character increases with the molecular weight of the fatty
acids.
Soda soaps are insoluble in concentrated caustic lyes, and, for the most
part, in strong solutions of sodium chloride, hence the addition of
caustic soda or brine to a solution of soda soap causes the soap to
separate out and rise to the surface. Addition of brine to a solution of
potash soap, on the other hand, merely results in double decomposition,
soda soap and potassium chloride being formed, thus:--
C_{17}H_{35}COOK + NaCl = C_{17}H_{35}COONa + KCl
potassium sodium sodium potassium
stearate chloride stearate chloride
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