The handbook of soap manufactureSimmons, W. H. (William Herbert)
Science
The handbook of soap manufacture
Simmons, W. H. (William Herbert)
Soap
If the dilution with water has been allowed to proceed too far, and too
fine a fit is produced, which would be denoted by the layer of soap not
leaving the trowel, a little caustic lye or brine may be very carefully
added and the whole well boiled until the desired condition is obtained.
A good pressure of steam is now applied to the pan, causing the contents
to swell as high as possible, this greatly facilitating the settling of
impurities; steam is then turned off, the pan covered, and the boil
allowed to rest for several days.
The art of fitting consists in leaving the contents of the pan in such a
condition that, on standing, all the impurities precipitate, and the
settled soap, containing the correct amount of water, is clear and
bright.
The above is a general practical outline of the ordinary soap-boiling
process. It may be modified or slightly altered according to the fancy
of the individual soap-maker or the particular material it is desired to
use. Fats and oils not only vary in the amount of alkali they absorb
during saponification, but also differ in the strength of the alkali
they require. Tallow and palm oil require lye of a density of 15 deg. to 18 deg.
Tw. (10 deg. to 12 deg. B.), but cocoa-nut oil alone would not saponify unless
the lye was more concentrated, 33 deg. to 42 deg. Tw. (20 deg. to 25 deg. B.).
Cotton-seed oil requires weak lyes for saponification, and, being
difficult to saponify alone even with prolonged boiling, is generally
mixed with animal fat.
When fats are mixed together, however, their varying alkali requirements
become modified, and once the saponification is begun with weak lye,
other materials are induced to take up alkali of a strength with which
alone they would not combine.
It is considered the best procedure to commence the pasting or
saponification with weak lye.
In order to economise tank space, it is the general practice to store
strong caustic lye (60 deg. to 70 deg. Tw., 33 deg. to 37 deg. B.) and to dilute it as
it is being added to the soap-pan by the simultaneous addition of water.
Many manufacturers give all their soap a "brine wash" to remove the last
traces of glycerine and free the soap from carbonates. This operation
takes place prior to "fitting"; sufficient water is added to the boiling
soap to "close" it and then brine is run in to "grain" it.
After resting, the liquor is withdrawn.
Having described the necessary operations in general, we will now
consider their application to the preparation of various kinds of hard
soap.
_Curd Soaps._--Tallow is largely used in the manufacture of white curd
soaps, but cocoa-nut oil sometimes enters into their composition.
Public-domain text, read in full here on John Shaqi.
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