The handbook of soap manufactureSimmons, W. H. (William Herbert)
Science
The handbook of soap manufacture
Simmons, W. H. (William Herbert)
Soap
Some of the English mottled soaps, especially those made from materials
which give a yellow-coloured ground, are bleached by soaking in brine,
or pickling in brine containing 2 per cent. of bleach liquor. The
resultant soap has a white ground and is firm. The bleach liquor may be
made by mixing 1 cwt. bleaching powder with 10 cwts. of soda ash
solution (15 deg. Tw., 10 deg. B.), allowing to settle, and using the clear
liquid, or by mixing 2 parts soda ash solution with 1 part of bleaching
powder solution, both solutions being 30 deg. Tw. (18.8 deg. B.).
_Milling-base._--The materials generally used are tallows and cocoa-nut
oils of the finest quality. The tallow is thoroughly saponified first,
and the graining is performed by the aid of caustic soda lye in
preference to salt. The half-spent lyes are withdrawn, and the cocoa-nut
oil added to the pan. This is saponified, and when the saponification is
complete, "boiling-on-strength" is proceeded with. Special care should
be devoted to the "boiling-on-strength" operation--its value in good
soap-making cannot be over-rated--and perfect saponification must be
ensured. The half-spent lyes are allowed to deposit during the night,
and the soap must be carefully examined next morning to ascertain if any
alkali has been absorbed. If the caustic taste is permanent the
strengthening operation is complete, but should any caustic have been
absorbed, further addition of alkali must be made and the boiling
continued. These remarks apply equally to all soaps.
The soap, when ready, is fitted.
Bleached palm oil, olive oil, castor oil and lard are also employed in
the production of special milling soap bases, a palm oil soap being
specially suitable for the production of a violet-scented toilet soap.
_Yellow Household Soaps._ (_a_) _Bar Soaps._--These are made from tallow
with an admixture of from 15-25 per cent. rosin. The best quality is
known in the South and West of England as Primrose Soap, but is
designated in the North of England by such names as Golden Pale,
Imperial Pale, Gold Medal Pale, etc. Tallow alone produces a very hard
soap of inferior lathering qualities; but rosin combines with alkali to
form a soft body, which, although not a soap in the strict sense of the
term, is readily soluble in water, and in admixture with the durable
tallow soap renders it more soluble in water and thereby increases its
lathering properties.
The rosin may be added to the soap-pan after a previous partial
saponification with soda ash, and removal of colouring matter, and
finally saponified with caustic soda lye, or, as is more generally
adopted, as a rosin change. The pan is opened with caustic soda lye and
saturation of the rosin takes place rapidly; when completely saponified
it is grained with salt, and the coloured lye allowed to deposit and
finally withdrawn.
The four operations already detailed apply to this soap.
Public-domain text, read in full here on John Shaqi.
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