The handbook of soap manufactureSimmons, W. H. (William Herbert)
Science
The handbook of soap manufacture
Simmons, W. H. (William Herbert)
Soap
Soap intended to be liquored with silicate of soda should be distinctly
strong in free alkali; the crystalline nature of the soap is increased
thereby, and the mottled effect intensified. Some makers, however, fit
the soap coarsely and allow a nigre to deposit; then, after removing the
nigre, or transferring the settled soap to another copper, containing
scraps of mottled soap, get the soap into a condition for mottling, and
add the silicate of soda solution. To every 1 cwt. of soap, 28 lb. of
silicate of soda solution, 32-1/2 deg. Tw. (20 deg. B.) is added, whilst
boiling; the strength of the silicate solution, however, will depend
upon the proportion of cocoa-nut oil and palm-kernel oil present in the
charge. Many soap-makers use 20 deg. Tw. (13 deg. B.) (cold) silicate solution,
whilst others prefer 140 deg. Tw. (59.5 deg. B.), with the gradual addition of
water to the soap, kept boiling, until the product is in the correct
mottling condition, and others, again, use bleach liquor, soda crystals,
pearl ash, and salt, together with silicate solution.
Considerable skill and experience is necessary to discern when the soap
acquires the correct mottling state. It should drop off the spatula in
large thick flakes, take considerable time to set, and the surface
should not be glossy.
When this mottling condition has been obtained, the colouring matter,
which would be ultramarine for the blue mottled and manganese dioxide
for the grey mottled soap (3-4 lb. ultramarine or 1-3 lb. manganese
dioxide being sufficient for 1 ton of soap), is mixed with a little
water and added to the boiling soap--the boiling is continued until all
is thoroughly amalgamated, and when the steam is shut off the contents
of the pan are ready for cleansing.
Mottled soap is run into wooden frames, which, when full, are covered
over and allowed to cool very gradually. On cooling slowly, large
crystals are produced which result in a distinct bold mottle; if the
cooling is too rapid, a small crystal is obtained and the mottle is not
distributed, resulting in either a small mottle, or no mottle at all,
and merely a general coloration. In fact, the entire art of mottling
soap consists in properly balancing the saline solutions and colouring
matter, so that the latter is properly distributed throughout the soap,
and does not either separate in coloured masses at the bottom of the
frame, or uniformly colour the whole mass.
A sample of the soap should test 45 per cent. fatty acids, and the
amount of salt would range from 1/2 to 1 per cent.
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