The handbook of soap manufactureSimmons, W. H. (William Herbert)
Science
The handbook of soap manufacture
Simmons, W. H. (William Herbert)
Soap
_Liquoring of Soaps._--This consists of the addition of various alkaline
solutions to soap to produce different qualities, and is best performed
in the crutching machines, although it is in some instances carried out
in the frames. In the history of soap-making a large number and variety
of substances have been suggested for the purpose of accomplishing some
real or supposed desirable effect when added to soap. Many of these have
had only a very short existence, and others have gradually fallen out of
use.
Amongst the more practical additions most frequently adopted may be
mentioned carbonate of soda, silicate of soda, and pearl ash (impure
carbonate of potash). The carbonate of soda may be used in the form of
"soda crystals," which, containing 62.9 per cent. of water, dissolves in
its own water of crystallisation on heating, and is in that manner added
to the hot soap. In the case of weak-bodied soap, this addition gives
firmness and tends to increase the detergent qualities.
The soda carbonate may also be added to soap as a solution of soda ash
(58 deg. alkali) either concentrated, 62 deg. Tw. (34 deg. B.), or of various
strengths from 25 deg. Tw. (16 deg. B.) upwards. This solution stiffens and
hardens soap, and the addition, which must not be excessive, or
efflorescence will occur, is generally made at a temperature of 140 deg. F.
(60 deg. C.). Care should always be taken in the choice of solutions for
liquoring. Strong soda ash solution with a firm soap will result in a
brittle product, whereas the texture of a weak soap would be greatly
improved by such addition.
A slight addition of a weak solution of pearl ash, 4 deg.-8 deg. Tw. (2.7-5.4 deg.
B.), improves the appearance of many soaps intended for household
purposes.
For yellow soaps, containing a low percentage of fatty acids, solutions
of silicate of soda of varying strengths are generally used.
It is always advisable to have a test sample made with the soap to
ascertain what proportion and what strength of sodium silicate solution
is best suited for the grade of soap it is desired to produce. It is
important that the soap to be "silicated" should be distinctly alkaline
(_i.e._, have a distinct caustic taste), or the resultant soap is liable
to become like stone with age. The alkaline silicate of soda (140 deg. Tw.,
59.5 deg. B.) is the quality most convenient for yellow soaps; this may be
diluted to the desired gravity by boiling with water. For a reduction of
3-4 per cent. fatty acids content, a solution of 6 deg. Tw. (4 deg. B.)
(boiling) is most suitable, and if the reduction desired is greater, the
density of the silicate solution should be increased; for example, to
effect a reduction of 20 per cent. fatty acids content, a solution of
18 deg. Tw. (12 deg. B.) (boiling) would probably be found to answer.
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