The handbook of soap manufactureSimmons, W. H. (William Herbert)
Science
The handbook of soap manufacture
Simmons, W. H. (William Herbert)
Soap
In some instances 140 deg. Tw. (59.5 deg. B.) silicate may be added; experiment
alone will demonstrate the amount which can be satisfactorily
incorporated without the soap becoming "open," but 1/10 of the quantity
of soap taken is practically a limit, and it will be found that the
temperature should be low; the same quantity of silicate at different
temperatures does not produce the same result. Various other strengths
of sodium silicate are employed, depending upon the composition and body
of the soap base--neutral silicate 75 deg. Tw. (39.4 deg. B.) also finds favour
with some soap-makers. Mixtures of soda crystals or soda ash solution
with silicate of soda solution are used for a certain grade of soap,
which is crutched until smooth and stiff. Glauber's salt (sodium
sulphate) produces a good smooth surface when added to soap, but, owing
to its tendency to effloresce more quickly than soda carbonate, it is
not so much used as formerly.
Common salt sometimes forms an ingredient in liquoring mixtures.
Potassium chloride and potassium silicate find a limited use for
intermixing with soft soaps.
It will be readily understood that hard and fast rules cannot be laid
down for "liquoring" soap, and the correct solution to be employed can
only be ascertained by experiment and experience, but the above
suggestions will prove useful as a guide towards good results. A smooth,
firm soap of clear, bright, glossy appearance is what should be aimed
at.
_Filling._--Some low-grade soaps contain filling, which serves no useful
purpose beyond the addition of weight. Talc is the most frequently used
article of this description. It consists of hydrated silicate of
magnesium and, when finely ground, is white and greasy to the touch. The
addition of this substance to the hot soap is made by suspending it in
silicate of soda solution.
Whatever filling material is used, it is important that the appearance
of the soap should not be materially altered.
_Neutralising, Colouring and Perfuming._--The free caustic alkali in
soap, intended for toilet or laundry purposes, is usually neutralised
during the cleansing, although some soap manufacturers prefer to
accomplish this during the milling operation. Various materials have
been recommended for the purpose, those in most general use being sodium
bicarbonate, boric acid, cocoa-nut oil, stearic acid, and oleic acid.
The best method is the addition of an exact quantity of sodium
bicarbonate (acid sodium carbonate), which converts the caustic alkali
into carbonate. The reaction may be expressed by the equation:--
NaOH + NaHCO_{3} = Na_{2}CO_{3} + H_{2}O
Caustic soda Bicarbonate of soda Carbonate of soda Water
Boric acid in aqueous or glycerine solutions, and borax (biborate of
soda) are sometimes used, but care is necessary in employing these
substances, as any excess is liable to decompose the soap.
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