The handbook of soap manufactureSimmons, W. H. (William Herbert)
Science
The handbook of soap manufacture
Simmons, W. H. (William Herbert)
Soap
The chief constituents of the oil are anethol, methyl chavicol,
d-pinene, l-phellandrene, and in older oils, the oxidation products of
anethol, _viz._ anisic aldehyde and anisic acid. Since anethol is the
most valuable constituent, and the solidifying point of the oil is
roughly proportional to its anethol content, oils with a higher
solidifying point are the best.
_Aspic oil_, from the flowers of Lavandula spica, obtained from France
and Spain, and extensively employed in perfuming household and cheap
toilet soaps; also frequently found as an adulterant in lavender oil.
Specific gravity at 15 deg. C., 0.904-0.913; optical rotation, French,
dextro-rotatory up to +4 deg., rarely up to +7 deg., Spanish, frequently
slightly laevo-rotatory to -2 deg., or dextro-rotatory up to +7 deg.; esters,
calculated as linalyl acetate, 2 to 6 per cent.; most oils are soluble
in 65 per cent. alcohol 1 in 4, in no case should more than 2.5 volumes
of 70 per cent. alcohol be required for solution.
The chief constituents of the oil are: linalol, cineol, borneol,
terpineol, geraniol, pinene, camphene and camphor.
_Bay oil_, distilled from the leaves of Pimenta acris, and obtained from
St. Thomas and other West Indian Islands. It is used to some extent as a
perfume for shaving soaps, but chiefly in the Bay Rhum toilet
preparation. Specific gravity at 15 deg. C., 0.965-0.980; optical rotation,
slightly laevo-rotatory up to -3 deg.; phenols, estimated by absorption with
5 per cent. caustic potash solution, from 45 to 60 per cent.; the oil is
generally insoluble in 90 per cent. alcohol, though when freshly
distilled it dissolves in its own volume of alcohol of this strength.
The oil contains eugenol, myrcene, chavicol, methyl eugenol, methyl
chavicol, phellandrene, and citral.
_Bergamot oil_, obtained by expression from the fresh peel of the fruit
of Citrus Bergamia, and used very largely for the perfuming of toilet
soaps. Specific gravity at 15 deg. C., 0.880-0.886; optical rotation, +10 deg.
to +20 deg.; esters, calculated as linalyl acetate, 35-40 per cent., and
occasionally as high as 42-43 per cent.; frequently soluble in 1.5 parts
of 80 per cent. alcohol, or failing that, should dissolve in one volume
of 82.5 or 85 per cent. alcohol. When evaporated on the water-bath the
oil should not leave more than 5-6 per cent. residue.
Among the constituents of this oil are: linalyl acetate, limonene,
dipentene, linalol, and bergaptene.
_Bitter Almond Oil._--The volatile oil obtained from the fruit of
_Amygdalus communis_. Specific gravity at 15 deg. C., 1.045-1.06; optically
inactive; refractive index at 20 deg. C., 1.544-1.545; boiling point,
176-177 deg. C.; soluble in 1 or 1.5 volumes of 70 per cent. alcohol.
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