The handbook of soap manufactureSimmons, W. H. (William Herbert)
Science
The handbook of soap manufacture
Simmons, W. H. (William Herbert)
Soap
The oil consists almost entirely of benzaldehyde which may be estimated
by absorption with a hot saturated solution of sodium bisulphite. The
chief impurity is prussic acid, which is not always completely removed.
This may be readily detected by adding to a small quantity of the oil
two or three drops of caustic soda solution, and a few drops of ferrous
sulphate solution containing ferric salt. After thoroughly shaking,
acidulate with dilute hydrochloric acid, when a blue coloration will be
produced if prussic acid is present.
The natural oil may frequently be differentiated from artificial
benzaldehyde by the presence of chlorine in the latter. As there is now
on the market, however, artificial oil free from chlorine, it is no
longer possible, by chemical means, to distinguish with certainty
between the natural and the artificial product. To test for chlorine in
a sample, a small coil of filter paper, loosely rolled, is saturated
with the oil, and burnt in a small porcelain dish, covered with an
inverted beaker, the inside of which is moistened with distilled water.
When the paper is burnt, the beaker is rinsed with water, filtered, and
the filtrate tested for chloride with silver nitrate solution.
_Canada snake root oil_, from the root of Asarum canadense. Specific
gravity at 15 deg. C., 0.940-0.962; optical rotation, slightly laevo-rotatory
up to -4 deg.; refractive index at 20 deg. C., 1.485-1.490; saponification
number, 100-115; soluble in 3 or 4 volumes of 70 per cent. alcohol.
The principal constituents of the oil are a terpene, asarol alcohol,
another alcohol, and methyl eugenol. The oil is too expensive to be used
in other than high-class toilet soaps.
_Cananga_ or _Kananga oil_, the earlier distillate from the flowers of
Cananga odorata, obtained chiefly from the Philippine Islands. Specific
gravity at 15 deg. C., 0.910-0.940; optical rotation, -17 deg. to -30 deg.;
refractive index at 20 deg. C., 1.4994-1.5024; esters, calculated as linalyl
benzoate, 8-15 per cent.; soluble in 1.5 to 2 volumes of 95 per cent.
alcohol, but becoming turbid on further addition.
The oil is qualitatively similar in composition to Ylang-Ylang oil, and
contains linalyl benzoate and acetate, esters of geraniol, cadinene, and
methyl ester of p-cresol.
_Caraway oil_, distilled from the seeds of Carum carui. Specific gravity
at 15 deg. C., 0.907-0.915; optical rotation, +77 deg. to +79 deg.; refractive index
at 20 deg. C., 1.485-1.486; soluble in 3 to 8 volumes of 80 per cent.
alcohol. The oil should contain 50-60 per cent. of carvone, which is
estimated by absorption with a saturated solution of neutral sodium
sulphite. The remainder of the oil consists chiefly of limonene.
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