The History and Practice of the Art of PhotographySnelling, Henry Hunt
History
The History and Practice of the Art of Photography
Snelling, Henry Hunt
Daguerreotype; Photography
The prismatic impression on paper spread with the chloride of silver is
often very beautifully tinted, the intensity of color varying with the
kind of muriate used. Spread paper with muriate of ammonia or baryta
and you obtain a range of colors nearly corresponding with the natural
hues of the prismatic spectrum. Under favorable circumstances the mean
red ray, leaves a red impression, which passes into a green over the
space occupied by the yellow rays. Above this a leaden hue is
observed, and about the mean blue ray, where the action is greatest, it
rapidly passes through brown into black, and through the most
refrangible rays it gradually declines into a bluish brown, which tint
is continued throughout the invisible rays. At the least refrangible
end of the spectrum, the very remarkable phenomenon has been observed,
of the extreme red rays exerting a protecting influence, and preserving
the paper from that change, which it would otherwise undergo, under the
influence of the dispersed light which always surrounds the spectrum.
Not only the extreme red ray exerts this very peculiar property, but
the ordinary red ray through nearly its whole length.
In photographic drawing this salt is of the utmost importance. Mr.
Talbot's application of it will be given hereafter in another portion
of this work.
IODIDE OF SILVER--Perfectly pure, undergoes very little change under
the influence of light or heat; but if a very slight excess of the
nitrate of silver be added it becomes infinitely more sensitive than
the chloride.
The spectrum impressed upon paper prepared with a weak solution of the
hydriodate of potash presents some very remarkable peculiarities. The
maximum of intensity is found at the edge of the most refrangible
violet rays, or a little beyond it, varying slightly according to the
kind of paper used, and the quantity of free nitrate of silver present.
The action commences at a point nearly coincident with the mean red of
the luminous spectrum, where it gives a dull ash or lead color, while
the most refrangible rays impress a ruddy snuff-brown, the change of
tint coming on rather suddenly about the end of the blue or beginning
of the violet rays of the luminous spectrum. Beyond the extreme violet
rays, the action rapidly diminishes, but the darkening produced by
these invisible rays, extends a very small space beyond the point at
which they cease to act on the chloride of silver.
In its photographic application, it is, alone, of very little use; but
in combination with other reagents it becomes exquisitely sensitive.
With gallic acid and the ferrocyanate of potash it forms two of the
most sensitive photographic solutions with which we are acquainted.
These are used in the calotype process.
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