The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
Combustibility then, according to this view of the subject, depends
upon a principle or material substance, existing in every combustible
body, and dissipated during the combustion. This substance was
considered to be absolutely the same in all combustible bodies
whatever; hence the difference between combustible bodies proceeded
from the other principle or number of principles with which this common
substance is combined. In consequence of this identity Stahl invented
the term _phlogiston_, by which he denoted this common principle of
combustible bodies. Inflammation, with the several phenomena that
attend it, depended on the gradual separation of this principle,
which being once separated, what remained of the body could no
longer be an inflammable substance, but must be similar to the other
kinds of matter. It was this opinion that combustibility is owing
to the presence of phlogiston, and inflammation to its escape, that
constituted the peculiar theory of Beccher, and which was afterwards
illustrated by Stahl with so much clearness, and experiments to prove
its truth were advanced by him of so much force, that it came to be
distinguished by the name of the Stahlian theory.
The identity of phlogiston in all combustible bodies was founded upon
observations and experiments of so decisive a nature, that after the
existence of the principle itself was admitted, they could not fail
to be satisfactory. When phosphorus is made to burn it gives out a
strong flame, much heat is evolved, and the phosphorus is dissipated
in a white smoke: but if the combustion be conducted within a glass
vessel of a proper shape, this white smoke will be deposited on the
inside of the glass; it quickly absorbs moisture from the atmosphere,
and runs into an acid liquid, known by the name of phosphoric acid.
If this liquid be put into a platinum crucible, and gradually heated
to redness, the water is dissipated, and a substance remains which,
on cooling, congeals into a transparent colourless body like glass:
this is dry _phosphoric_ acid. If now we mix phosphoric acid with
a quantity of charcoal powder, and heat it sufficiently in a glass
retort, taking care to exclude the external air, a _portion_ or the
_whole_ of the charcoal will disappear, and phosphorus will be formed
possessed of the same properties that it had before it was subjected
to combustion. The conclusion deduced from this process appeared
irresistible; the charcoal, or a portion of it, had combined with the
phosphoric acid, and both together had constituted phosphorus.
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