The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
This very crude opinion of the earthy nature of phlogiston, appears to
have been deduced from the insolubility of most combustible substances
in water. If we except alcohol, and ether, and gums, very few of
them are capable of being dissolved in that liquid. Thus the metals,
sulphur, phosphorus, oils, resins, bitumens, charcoal, &c., are well
known to be insoluble. Now, at the time that Beccher and Stahl lived,
insolubility in water was considered as a character peculiar to earthy
bodies; and as those bodies which contain a great deal of phlogiston
are insoluble in water, though the other constituents be very soluble
in that liquid, it was natural enough to conclude that phlogiston
itself was of an earthy nature.
But though the opinions of chemists about the nature and properties
of phlogiston in a separate state were unsettled, no doubts were
entertained respecting its existence, and respecting its identity in
all combustible bodies. Its presence or its absence produced almost
all the changes which bodies undergo. Hence chemistry and combustion
came to be in some measure identified, and a theory of combustion was
considered as the same thing with a theory of chemistry.
Metals were compounds of _calces_ and phlogiston. The different
species of metals depend upon the different species of calx which each
contains; for there are as many _calces_ (each simple and peculiar) as
there are metals. These calces are capable of uniting with phlogiston
in indefinite proportions. The calx united to a little phlogiston still
retains its earthy appearance--a certain additional portion restores
the calx to the state of a metal. An enormous quantity of phlogiston
with which some calces, as calx of manganese, are capable of combining,
destroys the metallic appearance of the body, and renders it incapable
of dissolving in acids.
The affinity between a metallic calx and phlogiston is strong; but the
facility of union is greatly promoted when the calx still retains a
little phlogiston. If we drive off the whole phlogiston we can scarcely
unite the calx with phlogiston again, or bring it back to the state of
a metal: hence the extreme difficulty of reducing the calx of zinc, and
even the red calx of iron.
The various colours of bodies are owing to phlogiston, and these
colours vary with every alteration in the proportion of phlogiston
present.
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