The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
Many chemical papers of Eller are to be found in the memoirs of the
Berlin Academy. They were of sufficient importance, at the time when
he published them, to add considerably to his reputation, though not
sufficiently so to induce me to give a catalogue of them here. I am
not aware of any chemical discovery for which we are indebted to him;
but have been induced to give this brief notice of him, because he is
usually associated with Pott and Margraaf, making with them the three
celebrated chemists who adorned Berlin, during the splendid reign of
Frederick the Great.
Andrew Sigismund Margraaf was born in Berlin, in the year 1709, and
acquired the first principles of chemistry from his father, who was
an apothecary in that city. He afterwards studied under Neumann, and
travelling in quest of information to Frankfort, Strasburg, Halle, and
Freyburg, he returned to Berlin enriched with all the knowledge of his
favourite science which at that time existed. In 1760, on the death
of Eller, he was made director of the physical class of the Berlin
Academy of Sciences. He died in the year 1782, in the seventy-third
year of his age. He gradually acquired a brilliant reputation in
consequence of the numerous chemical papers which he successively
published, each of which usually contained a new chemical fact, of
more or less importance, deduced from a set of experiments generally
satisfactory and convincing. His papers have a greater resemblance
to those of Scheele than of any other chemist to whom we can compare
them. He may be considered as in some measure the beginner of chemical
analysis; for, before his time, the chemical analysis of bodies had
hardly been attempted. His methods, as might have been expected,
were not very perfect; nor did he attempt numerical results. His
experiments on phosphorus and on the method of extracting it from urine
are valuable; they communicated the first accurate notions relative
to this substance and to phosphoric acid. He first determined the
properties of the earth of alum, now known by the name of _alumina_;
showed that it differed from every other, and that it existed in clay,
and gave to that substance its peculiar properties. He demonstrated
the peculiar nature of soda, the base of common salt, which Pott had
called in question, and thus verified the conclusions of Duhamel. He
gives an easy process for obtaining pure silver from the chloride of
that metal: his method is to dissolve the pure chloride of silver in a
solution of caustic ammonia, and to put into the liquid a sufficient
quantity of pure mercury; the silver is speedily reduced and converted
into an amalgam, and when this amalgam is exposed to a red heat the
mercury is driven off and pure silver remains. The usual method of
reducing the chloride of silver is to heat it in a crucible with a
sufficient quantity of carbonate of potash, a process which was first
recommended by Kunkel. But it is scarcely possible to prevent the loss
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