The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
of a portion of the silver when the chloride is reduced in this way.
The modern process is undoubtedly the simplest and the best, to reduce
it by means of hydrogen. If a few pieces of zinc be put into the bottom
of a beer-glass and some dilute sulphuric acid be poured over it an
effervescence takes place, and hydrogen gas is disengaged. Chloride of
silver, placed above the zinc in the same glass, is speedily reduced by
this hydrogen and converted into metallic silver.
Margraaf’s chemical papers, down to the time of publication, were
collected together, translated into French and published at Paris
in the year 1762, in two very small octavo volumes, they consist of
twenty-six different papers: some of the most curious and important
of which are those that have been just particularized. Several other
papers written by him appeared in the memoirs of the Berlin Academy,
after this collection of his works was published, particularly “A
demonstration of the possibility of drawing fixed alkaline salts
from tartar by means of acids, without employing the action of a
violent fire.” It was this paper, probably, that led Scheele, a few
years after, to his well-known method of obtaining tartaric acid, a
modification of which is still followed by manufacturers.
“Observations concerning a remarkable volatilization of a portion of
a kind of stone known by the names of flosse, flusse, fluor spar, and
likewise by that of hesperos: which volatilization was effectuated by
means of acids.” Pott had already shown the value of fluor spar as a
flux. Three years after the appearance of Margraaf’s paper, Scheele
discovered the nature of fluor spar, and first drew the attention of
chemists to the peculiar properties of fluoric acid.
In France, in consequence chiefly of the regulations established in
the Academy of Sciences, in the year 1699, a race of chemists always
existed, whose specific object was to cultivate chemistry, and extend
and improve it. The most eminent of these chemical labourers, after the
Stahlian theory was fully admitted in France till its credit began to
be shaken, were Reaumur, Hellot, Duhamel, Rouelle, and Macquer. Besides
these, who were the chief chemists in the academy, there were a few
others to whom we are indebted for chemical discoveries that deserve to
be recorded.
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