The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
He was without doubt one of the most eminent men of the age in which
he lived; but his merits as a chemist will chiefly be remembered
in consequence of his being the first person who demonstrated
by satisfactory evidence the peculiar nature of soda, which had
been previously confounded with potash. His merits as a vegetable
physiologist and agriculturist were of a very high order.
Peter Joseph Macquer was born at Paris, in 1718. His father, Joseph
Macquer, was descended from a noble Scottish family, which had
sacrificed its property and its country, out of attachment to the
family of the Stuarts.[183] Young Macquer made choice of medicine as
a profession, and devoted himself chiefly to chemistry, for which
he showed early a decided taste. He was admitted a member of the
Academy of Sciences in the year 1745, when he was twenty-seven years
of age. Original researches in chemistry, the composition of chemical
elementary works, and the study of the arts connected with chemistry,
occupied the whole remainder of his life.
[183] I do not know what the true name was of which Macquer is a
corruption. Ker is a Scottish name belonging to two noble families,
the Duke of Roxburgh and the Marquis of Lothian; but I am not aware of
M’Ker being a Scottish name: besides, neither of these families was
attached to the house of Stuart.
His first paper treated of the effect produced by heating a mixture of
saltpetre and white arsenic. It was previously known, that when such a
mixture is distilled nitric acid comes over tinged with a blue colour;
but nobody had thought of examining the residue of this distillation.
Macquer found it soluble in water and capable of crystallizing into a
neutral salt composed of potash (the base of saltpetre), and an acid
into which the arsenic was changed by the nitric acid communicating
oxygen to it.
Macquer found that a similar salt might be obtained with soda or
ammonia for its base. Thus he was the first person who pointed out
the existence of arsenic acid, and ascertained the properties of some
of the salts which it forms. But he made no attempt to obtain arsenic
acid in a separate state, or to determine its properties. That very
important step was reserved for Scheele, for Macquer seems to have had
no suspicion of the true nature of the salt which he had formed.
Public-domain text, read in full here on John Shaqi.
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