The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
It was during his residence in Glasgow, between the years 1759 and
1763, that he brought to maturity those speculations concerning the
combination of _heat_ with _matter_, which had frequently occupied
a portion of his thoughts. It had long been known that ice has the
property of continuing always at the temperature of 32° till it be
melted. This happens equally though it be placed in contact with the
warm hand or surrounded with bodies many degrees hotter than itself.
The hotter the bodies are that surround it, the sooner is it melted;
but its temperature during the whole process of melting, continues
uniformly the same. Yet, during the whole process of melting, it is
constantly robbing the surrounding bodies of heat; for it makes them
colder, without acquiring itself any sensible heat.
Dr. Black had some vague notion that the heat so received by the ice,
during its conversion into water, was not lost, but was contained in
the water. This opinion was founded chiefly on a curious observation
of Fahrenheit, recorded by Boerhaave; namely, that water might in some
cases be made considerably colder than melting snow, without freezing.
In such cases, when disturbed it would freeze in a moment, and in the
act of freezing always gave out a quantity of heat. This opinion was
confirmed by observing the slowness with which water is converted
into ice, and ice into water. A fine winter-day of sunshine is never
sufficient to clear the hills of snow; nor is one frosty night capable
of covering the ponds with a thick coating of ice. The phenomena
satisfied him that much heat was absorbed and fixed in the water which
trickles from wreaths of snow, and that much heat emerged from it while
water was slowly converted into ice; for during a thaw the melting snow
is always colder than the air, and must, therefore, be always receiving
heat from it; while, during a frost, the air is always colder than the
freezing water, and must therefore be always receiving heat from it.
These observations, and many others which it is needless to state,
satisfied Dr. Black that when ice is converted into water it unites
with a quantity of heat, without increasing in temperature; and that
when water is frozen into ice it gives out a quantity of heat without
diminishing in temperature. The heat thus combined is the cause of the
fluidity of the water. As it is not sensible to the thermometer, Dr.
Black called it _latent heat_. He made an experiment to determine the
quantity of heat necessary to convert ice into water. This he estimated
by the length of time necessary to melt a given weight of ice,
measuring how much heat entered into the same weight of water, reduced
as nearly to the temperature of ice as possible during the first
half-hour that the experiment lasted. As the ice continued during the
whole of its melting at the same temperature as at first, he concluded
that it would absorb, every half-hour that the process lasted, as much
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