The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
Inflammable air (hydrogen gas) is evolved when iron, zinc, or tin,
are dissolved in dilute sulphuric or muriatic acid. Iron yielded
about 1-22d part of its weight, of inflammable air, zinc about
1-23d or 1-24th of its weight, and tin about 1-44th of its weight.
The properties of the inflammable air were the same, whichever of
the three metals was used to procure it, and whether they were
dissolved in sulphuric or muriatic acids. When the sulphuric acid was
concentrated, iron and zinc dissolved in it with difficulty and only
by the assistance of heat. The air given out was not inflammable, but
consisted of sulphurous acid. These facts induced Mr. Cavendish to
conclude that the inflammable air evolved in the first case was the
unaltered _phlogiston_ of the metals, while the sulphurous acid evolved
in the second case, was a compound of the same phlogiston and a portion
of the acid, which deprived it of its inflammability. This opinion was
very different from that of Stahl, who considered combustible bodies as
compounds of phlogiston with acids or calces.
Cavendish found the specific gravity of his inflammable air about
eleven times less than that of common air. This determination is under
the truth; but the error is, at least in part, owing to the quantity
of water held in solution by the air, and which, as Mr. Cavendish
showed, amounted to about 1-9th of the weight of the air. He tried
the combustibility of the inflammable air, when mixed with various
proportions of common air, and found that it exploded with the greatest
violence when mixed with rather more than its bulk of common air.
Copper he found, when dissolved in muriatic acid by the assistance of
heat, yielded no inflammable air, but an air which lost its elasticity
when it came in contact with water. This _air_, the nature of which Mr.
Cavendish did not examine, was _muriatic acid gas_, the properties of
which were afterwards investigated by Dr. Priestley.
The _fixed air_ (_carbonic acid gas_) on which Mr. Cavendish made his
experiments was obtained by dissolving marble in muriatic acid. He
found that it might be kept over mercury for any length of time without
undergoing any alteration; that it was gradually absorbed by cold
water; and that 100 measures of water of the temperature 55° absorbed
103·8 measures of fixed air. The whole of the air thus absorbed was
separated again by exposing the water to a boiling heat, or by leaving
it for sometime in an open vessel. Alcohol (the specific gravity not
mentioned) absorbed 2¼ times its bulk of this air, and olive-oil about
1-3d of its bulk.
Public-domain text, read in full here on John Shaqi.
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